[N,N'-ethylenebis(3-tert-butyl-5-methylsalicylideneaminato)]oxovanadium(IV) | 198885-47-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [N,N'-ethylenebis(3-tert-butyl-5-methylsalicylideneaminato)]oxovanadium(IV)
• 英文别名: [N,N'-ethylenebis(o-tert-butyl-p-methylsalicylaldiminato)]oxovanadium(IV)；N,N'-ethylenebis(o-tert-butyl-p-methylsalicylaldiminato)oxovanadium
• CAS: 198885-47-1
• 化学式: C₂₆H₃₄N₂O₃V
• 分子量: 473.509
• InChiKey: RLFNJDJKLASPFN-HQRQQUDRSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(acetylacetonate)oxovanadium 、 N,N'-1,2-ethylenebis(3-tert-butyl-5-methylsalicylideneimine) 以 二氯甲烷 为溶剂， 生成 [N,N'-ethylenebis(3-tert-butyl-5-methylsalicylideneaminato)]oxovanadium(IV)
  参考文献：
  名称：

  [N,N'-Ethylenebis(3-tert-butyl-5-methylsalicylideneaminato)]oxovanadium(IV)

  摘要：

  [VO(C26H34N2O2)] was synthesized in order to study its reactivity in the oxygen-transfer catalysis of alkyl hydroperoxides to a wide array of substituted olefins, The geometry about the V center is nearly square pyramidal, with an axial oxo ligand and a four-coordinate substituted Schiff base ligand. The axial V-O bond distance of 1.592(3) Angstrom is indicative of double-bond character.

  DOI：

  10.1107/s0108270198003990

文献信息

• Cornman, Charles R.; Geiser-Bush, Katherine M.; Rowley, Stephen P., Inorganic Chemistry, 1997, vol. 36, # 27, p. 6401 - 6408
  作者：Cornman, Charles R.、Geiser-Bush, Katherine M.、Rowley, Stephen P.、Boyle, Paul D.

  DOI：——

  日期：——