(2,6-diisopropylphenyl)phenyl azide | 745024-77-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2,6-diisopropylphenyl)phenyl azide
• 英文别名: N₃(2,6-bis(2,6-diisopropylphenyl)phenyl)；N₃dippp；N3-2,6-(2,6-iPr2C6H3)2C6H3；1,1':3',1''-Terphenyl, 2'-azido-2,2'',6,6''-tetrakis(1-methylethyl)-；2-azido-1,3-bis[2,6-di(propan-2-yl)phenyl]benzene
• CAS: 745024-77-5
• 化学式: C₃₀H₃₇N₃
• 分子量: 439.644
• InChiKey: SAUCZMJNTMAKPT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.6
• 重原子数：
  33
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  14.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (2,6-diisopropylphenyl)phenyl azide 、 IPr*SiCl2 以 甲苯 为溶剂， 反应 48.0h， 以69%的产率得到[[1,3-Bis[2,6-di(propan-2-yl)phenyl]imidazol-1-ium-2-yl]-dichlorosilyl]-[2,6-bis[2,6-di(propan-2-yl)phenyl]phenyl]azanide
  参考文献：
  名称：

  N-Heterocyclic Carbene Stabilized Dichlorosilaimine IPr·Cl₂Si═NR

  摘要：

  N-Heterocyclic carbene stabilized dichlorosilaimine IPr center dot Cl2Si=N(Diip) (2) has been synthesized by the reaction of dichlorosilylene IPr center dot SiCl2 (1) with bis(2,6-diisopropylphenyl)carbodiimide (IPr = :C[N(2,6-i-Pr-2-C6H3)CH](2), Diip = 2,6-i-Pr-2-C6H3). Reaction of 1 with terphenyl azides also affords dichlorosilaimines IPr center dot Cl2Si=N(2,6-Diip(2)-C6H3) (3) and IPr center dot Cl2Si=N(2,6-Triip(2)-C6H3) (4) (Triip = 2,4,6-i-Pr-3-C6H2). Compounds 2-4 are stable under an inert atmosphere and were characterized by elemental analysis and NMR spectroscopic studies. The molecular structures of 2-4 were determined by single-crystal X-ray analysis.

  DOI：

  10.1021/om100737v

文献信息

• Strongly bent nickel imides supported by a chelating bis(N-heterocyclic carbene) ligand
  作者：Nicole D. Harrold、Gregory L. Hillhouse

  DOI：10.1039/c3sc51517f

  日期：——

  nickel-arylimido complexes of the type L2NiNAr supported by a new chelating bis(N-heterocyclic carbene) ligand are described, including experimental, structural, and computational data to validate this atypical binding motif. Upon oxidation the strongly bent imido complex undergoes C,C-coupling and dehydrogenation to afford a complex bearing an unusual diphenoquinonediimine ligand bridging two Ni(II) centers.

  描述了由新的螯合双（N-杂环卡宾）配体支持的L 2 Ni NAr型不寻常的弯曲镍-芳基酰亚胺络合物的合成和氧化还原反应性，包括实验，结构和计算数据，以验证这种非典型结合基序。氧化后，强烈弯曲的亚胺基络合物进行C，C偶联和脱氢反应，得到带有一个桥接两个Ni（II）中心的不寻常的二苯醌二亚胺配体的络合物。
• An indium(<scp>i</scp>) tetramer bound by anionic N-heterocyclic olefins: ambiphilic reactivity, transmetallation and a rare indium-imide
  作者：Samuel R. Baird、Emanuel Hupf、Ian C. Watson、Michael J. Ferguson、Eric Rivard

  DOI：10.1039/d2cc07006e

  日期：——

  An organometallic tetrahedron-shaped indium(I) tetramer [(MeIPrCH)In]4 (MeIPrCH = [(MeCNDipp)2CCH]−; Dipp = 2,6-iPr2C6H3) supported by anionic N-heterocyclic olefin (aNHO) ligands is reported. The monomeric unit of this species exhibits both Lewis acidic and basic character at indium, while the steric profile of the aNHO ligand enables isolation of a rare monomeric imide, RInNR′.

  由阴离子 N 支持的有机金属四面体形铟 ( I ) 四聚体 [( Me IPrCH)In] 4 ( Me IPrCH = [(MeCNDipp) 2 C CH] − ; Dipp = 2,6- i Pr 2 C 6 H 3 ) -报道了杂环烯烃 (aNHO) 配体。该物种的单体单元在铟处表现出路易斯酸性和碱性特征，而 aNHO 配体的空间结构能够分离稀有的单体酰亚胺 RInNR'。
• Two Types of Intramolecular Addition of an Al−N Multiple-Bonded Monomer LAlNAr‘ Arising from the Reaction of LAl with N₃Ar‘ (L = HC[(CMe)(NAr)]₂, Ar‘ = 2,6-Ar₂C₆H₃, Ar = 2,6-<i>i</i>Pr₂C₆H₃)
  作者：Hongping Zhu、Jianfang Chai、Vadapalli Chandrasekhar、Herbert W. Roesky、Jörg Magull、Denis Vidovic、Hans-Georg Schmidt、Mathias Noltemeyer、Philip P. Power、William A. Merrill

  DOI：10.1021/ja0475712

  日期：2004.8.1

  The reaction of beta-diketiminated aluminum(I) monomer LAl with a large bulky azide N3Ar' (L = HC(CMeNAr)2, Ar' = 2,6-Ar2C6H3, Ar = 2,6-iPr2C6H3) in the temperature range from -78 degrees C to room temperature affords two different isomers 2 and 3, which have been characterized by spectroscopic and X-ray structural analyses, as well as elemental analysis. The variable-temperature 1H NMR kinetic studies of this reaction indicate the existence of the monomer LAlNAr' (1) at low temperature and the thermal stability of the compounds increases in the order of 1 < 2 < 3.
• N-Heterocyclic Carbene Stabilized Dichlorosilaimine IPr·Cl₂Si═NR
  作者：Rajendra S. Ghadwal、Herbert W. Roesky、Carola Schulzke、Markus Granitzka

  DOI：10.1021/om100737v

  日期：2010.12.13

  N-Heterocyclic carbene stabilized dichlorosilaimine IPr center dot Cl2Si=N(Diip) (2) has been synthesized by the reaction of dichlorosilylene IPr center dot SiCl2 (1) with bis(2,6-diisopropylphenyl)carbodiimide (IPr = :C[N(2,6-i-Pr-2-C6H3)CH](2), Diip = 2,6-i-Pr-2-C6H3). Reaction of 1 with terphenyl azides also affords dichlorosilaimines IPr center dot Cl2Si=N(2,6-Diip(2)-C6H3) (3) and IPr center dot Cl2Si=N(2,6-Triip(2)-C6H3) (4) (Triip = 2,4,6-i-Pr-3-C6H2). Compounds 2-4 are stable under an inert atmosphere and were characterized by elemental analysis and NMR spectroscopic studies. The molecular structures of 2-4 were determined by single-crystal X-ray analysis.