N(1)-salicylidene-N(2)-cis-2,6-diphenyltetrahydrothiopyran-4-one azine | 622370-18-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: N(1)-salicylidene-N(2)-cis-2,6-diphenyltetrahydrothiopyran-4-one azine
• CAS: 622370-18-7
• 化学式: C₂₄H₂₂N₂OS
• 分子量: 386.517
• InChiKey: KPYKMBUTOPMLGX-PSWAGMNNSA-N

反应信息

• 作为反应物：
  描述：

  nickel(II) nitrate hexahydrate 、 N(1)-salicylidene-N(2)-cis-2,6-diphenyltetrahydrothiopyran-4-one azine 以 N,N-二甲基甲酰胺 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Studies on Binuclear Complexes of N(1)-Salicylidene-N(2)-cis-2,6-Diphenyltetrahydrothiopyran-4-one Azine

  摘要：

  A novel heterocyclic ligand, N(I)-salicylidene-N(2)-cis-2,6-diphenylte-trahydrothiopyran-4-one azine (HL) and its complexes with Ni(II) [Ni(NO3)(2), NiCl2 and Ni(ClO4)(2)], Co(II), Zn(II) and Fe(III) have been synthesized and characterized by elemental and spectral analyses. The spectral data along with magnetic susceptibility measurements, molar conductance and thermal analyses reveal that the ligand HL acts as a uni to negative bidentate ligand and the metal:ligand stoichiometry is 2:1 with Ni(II) and 2:2 with the other metal ions An X-ray (powder) diffraction study of the zinc complex shows that the complex crystallises in a triclinic lattice.

  DOI：

  10.1081/sim-120021928