| 936633-71-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 936633-71-5
• 化学式: C₉H₈NO₇SZn*Na
• 分子量: 362.611
• InChiKey: KGMPTWLBMXSFLG-LFDAPOSGSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,10-菲罗啉 、 以 甲醇 、 水 为溶剂， 以87%的产率得到[Zn(OC6H3(SO3Na)CHNCH2CO2)(1,10-phenanthroline)]
  参考文献：
  名称：

  Spectral characterization of novel ternary zinc(II) complexes containing 1,10-phenanthroline and Schiff bases derived from amino acids and salicylaldehyde-5-sulfonates

  摘要：

  A series of new ternary zinc(II) complexes [Zn(L1-10)(phen)], where phen is 1,10-phenanthroline and H2L1-10 = tridentate Schiff base ligands derived from the condensation of amino acids (glycine, L-phenylalanine, L-valine, L-alanine, and L-leucine) and salicylaldehyde-5-sulfonates (sodium salicylaldehyde-5-sulfonate and sodium 3-methoxy-salicylaldehyde-5-sulfonate), have been synthesized. The complexes were characterized by elemental analysis, IR, UV-vis, H-1 NMR, and C-13 NMR spectra. The IR spectra of the complexes showed large differences between v(as)(COO) and v(s)(COO), Delta v (v(as)(COO) - v(s)(COO)) of 191-225 cm(-1), indicating a monodentate coordination of the carboxylate group. Spectral data showed that in these ternary complexes the zinc atom is coordinated with the Schiff base ligand acts as a tridentate ONO moiety, coordinating to the metal through its phenolic oxygen, imine nitrogen, and carboxyl oxygen, and also with the neutral planar chelating ligand, 1,10-phenanthroline, coordinating through nitrogens. (C) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2006.09.012