picoxystrobin TP1 | 1429767-29-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: picoxystrobin TP1
• 英文别名: (E)-3-methoxy-2-[2-[[6-(trifluoromethyl)pyridin-2-yl]oxymethyl]phenyl]prop-2-enoic acid
• CAS: 1429767-29-2
• 化学式: C₁₇H₁₄F₃NO₄
• 分子量: 353.29
• InChiKey: HUGINNZOWWNDGC-JLHYYAGUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  25
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  68.6
• 氢给体数：
  1
• 氢受体数：
  8

文献信息

• 5-phenypyrimidines their preparation compositions comprising them and their use
  申请人：Gypser Andreas

  公开号：US20060148764A1

  公开（公告）日：2006-07-06

  5-Phenylpyrimidines of the formula I in which the substituents and the index are as defined below: R 1 ,R 2 are hydrogen, alkyl, haloalkyl, cycloalkyl, halocycloalkyl, alkenyl, haloalkenyl, alkynyl or haloalkynyl, and R 1 and R 2 together with the nitrogen atom to which they are attached may also form a saturated or unsaturated ring which may be interrupted by an ether, thio, sulfoxyl or sulfonyl group and may be substituted by one to four groups R a and/or R b ; R 3 is hydrogen, halogen, cyano, alkyl, haloalkyl, alkoxy, haloalkoxy or alkenyloxy; R 4 is hydrogen, halogen, cyano, hydroxyl, mercapto, azido, alkyl, alkenyl, alkynyl, haloalkyl, alkoxy, alkenyloxy, alkynyloxy, haloalkoxy, alkylthio, alkenylthio, alkynylthio, haloalkylthio, —ON═CR a R b , —CR c ═NOR a , —NR c N═CR a R b , —NR a R b , —NR c NR a R b , —NOR a , —NR c C(═NR c′ )NR a R b , —NR c C(═O)NR a R b , —NR a C(═O)R c , —NR a C(═NOR c )R c′ , —OC(═O)R c , —C(═NOR c )NR a R b , —CR c (═NNR a R b ), —C(═O)NR a R b or —C(═O)R c ; in which R a , R b and R c are as defined in the description; X is halogen, alkyl, alkoxy or haloalkyl; and m is an integer from 1 to 5; processes for preparing these compounds, compositions comprising them and their use for controlling harmful fungi are described.

  式I中的5-苯基嘧啶，其中取代基和指数定义如下：R1，R2为氢，烷基，卤代烷基，环烷基，卤代环烷基，烯基，卤代烯基，炔基或卤代炔基，而且R1和R2连同它们所连接的氮原子也可以形成一个饱和或不饱和的环，该环可以被醚，硫，亚硫氧基或磺酰基所中断，并且可以被一个到四个Ra和/或Rb基团取代；R3为氢，卤素，氰基，烷基，卤代烷基，烷氧基，卤代烷氧基或烯氧基；R4为氢，卤素，氰基，羟基，巯基，偶氮基，烷基，烯基，炔基，卤代烷基，烷氧基，烯氧基，炔氧基，卤代烷氧基，烷硫基，烯硫基，炔硫基，卤代烷硫基，-ON═CRaRb，-CRc═NORa，-NRcN═CRaRb，-NRaRb，-NRcNRaRb，-NORa，-NRcC(═NRc′)NRaRb，-NRcC(═O)NRaRb，-NRaC(═O)Rc，-NRaC(═NORc)Rc′，-OC(═O)Rc，-C(═NORc)NRaRb，-CRc(═NNRaRb)，-C(═O)NRaRb或-C(═O)Rc；其中Ra，Rb和Rc如描述中所定义；X为卤素，烷基，烷氧基或卤代烷基；m为1至5之间的整数；描述了制备这些化合物的方法，包括它们的组成物和用于控制有害真菌的用途。
• 5-PHENYLPYRIMIDINES, THEIR PREPARATION, COMPOSITIONS COMPRISING THEM AND THEIR USE
  申请人：GYPSER Andreas

  公开号：US20070149551A1

  公开（公告）日：2007-06-28

  5-Phenylpyrimidines of the formula I in which the substituents and the index are as defined below: R 1 ,R 2 are hydrogen, alkyl, haloalkyl, cycloalkyl, halocycloalkyl, alkenyl, haloalkenyl, alkynyl or haloalkynyl, and R 1 and R 2 together with the nitrogen atom to which they are attached may also form a saturated or unsaturated ring which may be interrupted by an ether, thio, sulfoxyl or sulfonyl group and may be substituted by one to four groups R a and/or R b ; R 3 is hydrogen, halogen, cyano, alkyl, haloalkyl, alkoxy, haloalkoxy or alkenyloxy; R 4 is hydrogen, halogen, cyano, hydroxyl, mercapto, azido, alkyl, alkenyl, alkynyl, haloalkyl, alkoxy, alkenyloxy, alkynyloxy, haloalkoxy, alkylthio, alkenylthio, alkynylthio, haloalkylthio, —ON═CRN a R b , —CR c ═NOR a , —NR c N═CR a R b , —NR a R b , —NR c NR a R b , —NOR a , —NR c C (═NR c′ )NR a R b , —NR c C(═O)NR a R b , —NR a C(═O)R c , —NR a C(═NOR c )R c′ , —OC (═O)R c , —C(═NOR c )NR a R b , —CR c (═NNR a R b ), —C (═O)NR a R b or —C(═O) R c ; in which R a , R b and R c are as defined in the description; X is halogen, alkyl, alkoxy or haloalkyl; and m is an integer from 1 to 5; processes for preparing these compounds, compositions comprising them and their use for controlling harmful fungi are described.

  公式I中的5-苯基嘧啶化合物，其中取代基和指数定义如下：R1、R2为氢、烷基、卤代烷基、环烷基、卤代环烷基、烯基、卤代烯基、炔基或卤代炔基，且R1和R2与它们附着的氮原子也可以形成饱和或不饱和环，该环可以被醚、硫、亚硫酰基或磺酰基中断，并且可以被一个到四个基团Ra和/或Rb取代；R3为氢、卤素、氰基、烷基、卤代烷基、烷氧基、卤代烷氧基或烯氧基；R4为氢、卤素、氰基、羟基、巯基、叠氮基、烷基、烯基、炔基、卤代烷基、烷氧基、烯氧基、炔氧基、卤代烷氧基、烷硫基、烯硫基、炔硫基、卤代烷硫基、-ON═CRNaRb，-CRc═NORa，-NRcN═CRaRb，-NRaRb，-NRcNRaRb，-NORa，-NRcC（═NRc'）NRaRb，-NRcC（═O）NRaRb，-NRaC（═O）Rc，-NRaC（═NORc）Rc'，-OC（═O）Rc，-C（═NORc）NRaRb，-CRc（═NNRaRb），-C（═O）NRaRb或-C（═O）Rc；其中Ra、Rb和Rc如描述中所定义；X为卤素、烷基、烷氧基或卤代烷基；m为1至5的整数；描述了制备这些化合物的过程、包含它们的组合物以及它们用于控制有害真菌的用途。
• Seed treatment compositions
  申请人：Syngenta Participations AG

  公开号：EP1767092A1

  公开（公告）日：2007-03-28

  An agrochemical composition for the treatment of plant propagation material, comprising at least two active ingredient components together with a suitable carrier, wherein component I is I) metalaxyl (= methyl N-(methoxyacetyl)-N-(2, 6-xylyl)-DL-alaninate) or metalaxyl-M (= methyl N-(mathoxyacetyl)-N- (2, 6-xylyl)-D- alaninate) and wherein component II is IIA) azoxystrobin (=methyl (E)-2-2-[6-(2-cyanophenoxy) pyrimidin-4-yloxy]phenyl}-3-methoxyacrylate) or IIB) picoxystrobin (= methyl (E)-3-methoxy-2- [2-(6-trifluoromethyl-2-pyridyloxymethyl)phanyl] acrylate) or IIC) kresoxim-methyl (= methyl (E)-methoxyimino [2-(o-tolyloxymethyl)phenyl]acetate).

  一种用于处理植物繁殖材料的农用化学品组合物，包括至少两种活性成分组分和一种合适的载体，其中组分I为I)甲霜灵(＝N-(甲氧基乙酰基)-N-(2，6-羟基)-DL-丙氨酸甲酯)或甲霜灵-M(＝N-(甲氧基乙酰基)-N-(2、(E)-2-2-[6-(2-氰基苯氧基)嘧啶-4-基氧基]苯基}-3-甲氧基丙烯酸甲酯）或 IIB) 吡唑醚菌酯（＝(E)-2-[3-甲氧基-2-[6-(2-氰基苯氧基)嘧啶-4-基氧基]苯基]-3-甲氧基丙烯酸甲酯）。3-甲氧基-2-[2-(6-三氟甲基-2-吡啶氧甲基)苯基]丙烯酸酯)或 IIC) Kresoxim-methyl (= (E)-甲氧基亚氨基[2-(邻甲苯氧甲基)苯基]乙酸甲酯)。
• Synergistic antifungal DDAC compostions
  申请人：Janssen Pharmaceutica NV

  公开号：EP1856977A2

  公开（公告）日：2007-11-21

  The present invention relates to synergistic antifungal compositions comprising didecyl ammonium chloride (DDAC) and a post-harvest antifungal agent selected from the group consisting of imazalil, boscalid, fenhexamid, pyrimethanil, thiophanate-methyl, triflumizole, azoxystrobin, dimoxystrobin, picoxystrobin, and pyraclostrobin for protecting plants, fruit or seeds against phytopathogenic fungi.

  本发明涉及一种增效抗真菌组合物，该组合物由十二烷基氯化铵（DDAC）和一种采后抗真菌剂组成，该抗真菌剂选自咪唑、啶虫脒、唑虫酰胺、嘧菌酯、甲基硫菌灵、三环唑、唑菌酯、二唑菌酯、吡唑醚菌酯和吡唑醚菌酯组成的组，用于保护植物、果实或种子免受植物病原真菌的侵害。
• Synergistic fungicidal mixtures and compositions comprising 5-fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidin-2(1H)-one for fungal control
  申请人：Adama Makhteshim Ltd.

  公开号：US10051862B2

  公开（公告）日：2018-08-21

  A fungicidal composition containing a fungicidally effective amount of the compound of Formula I: 5-fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidin-2(1H)-one, and at least one fungicide to provide synergistic control of selected fungi wherein the at least one fungicide is a multi-site inhibitor or a strobilurin inhibitor.

  一种杀菌组合物，含有杀菌有效量的式Ⅰ化合物： 5-氟-4-亚氨基-3-甲基-1-对甲基苯磺酰-3,4-二氢嘧啶-2(1H)-酮和至少一种杀真菌剂，可协同控制选定的真菌，其中至少一种杀真菌剂是多位点抑制剂或strobilurin 抑制剂。