| 67610-90-6

• CAS: 67610-90-6
• 化学式: C₁₆H₁₃Cl₂CoN₃
• 分子量: 377.199
• InChiKey: QFGPJFZASKXPGA-KAQIIPFASA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  6-甲基-2-吡啶甲醛 、 7-氨基喹啉 、 cobalt(II) chloride 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  线性三齿含氮配体的Co（II）和Ni（II）配合物

  摘要：

  描述了一些线性三齿含氮配体与镍（II）和钴（II）盐的单配体配合物。根据电子和红外光谱测量，式[Ni-（配体）X 2]的化合物（X ＝ Cl，Br，I或NCS）似乎是桥联的八面体化合物。另一方面，光谱结果表明类似的钴（II）化合物是单体五配位物种。报告了所描述化合物的磁数据，并详细给出了吡啶环振动区的红外光谱，这表明在所有情况下，配体均以三齿形式起作用。

  DOI：

  10.1016/s0020-1693(00)89623-1

文献信息

• Iron(II) and cobalt(II) complexes bearing N-((pyridin-2-yl)methylene)-quinolin-8-amine derivatives: Synthesis and application to ethylene oligomerization
  作者：Kefeng Wang、Katrin Wedeking、Weiwei Zuo、Dongheng Zhang、Wen-Hua Sun

  DOI：10.1016/j.jorganchem.2007.12.030

  日期：2008.3

  A series of tridentate N boolean AND N boolean AND N iron(II) and cobalt(II) complexes containing N-((pyridin-2-yl) methylene)-quinolin-8-amine derivatives were synthesized and characterized by elemental and spectroscopic analyses. The molecular structure of 1a was con. rmed by X-ray diffraction analyses. On treatment with modified methylaluminoxane, these metal complexes exhibited good catalytic activities up to 2.8 x 10(6) g mol(-1)(Fe) h(-1) for ethylene oligomerization, and butenes were the major products with nice selectivity for 1-C-4. The steric and electronic effects on catalytic activities of metal complexes were carefully investigated as well as the influence of various reaction parameters. In the catalytic system, Fe(II) complexes performed better catalytic activities than their Co(II) analogues. With ligands having bulky substituents, the better catalytic activity was observed in catalytic system of Fe(II) complex, however, the lower catalytic activity was obtained in catalytic system of Co(II) complexes. (C) 2008 Elsevier B.V. All rights reserved.