cis-{1,5-dibenzyl-3,7-diphenyl-1,5,3,7-diazadiphosphacyclooctane}dichloropalladium(II) | 145957-03-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cis-{1,5-dibenzyl-3,7-diphenyl-1,5,3,7-diazadiphosphacyclooctane}dichloropalladium(II)
• 英文别名: 1,5-dibenzyl-3,7-diphenyl-1,5,3,7-diazadiphosphocane;dichloropalladium
• CAS: 145957-03-5
• 化学式: C₃₀H₃₂Cl₂N₂P₂Pd
• 分子量: 659.871
• InChiKey: JEWXHEBCFLLVDC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  7.83
• 重原子数：
  37.0
• 可旋转键数：
  6.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  6.48
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  1,5-dibenzyl-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane 、 bis(benzonitrile)palladium(II) chloride 以 二氯甲烷 为溶剂， 以65%的产率得到cis-{1,5-dibenzyl-3,7-diphenyl-1,5,3,7-diazadiphosphacyclooctane}dichloropalladium(II)
  参考文献：
  名称：

  Synthesis and structural studies of molybdenum and palladium complexes of 1,5-diaza-3,7-diphosphacyclooctane ligands

  摘要：

  1,5-Diaza-3;7-diphosphacyclooctanes form 1:1 complexes with the metal fragments Mo(CO)(4) and PdCl2. Two of these products along with a parent heterocycle have been structurally characterized. The [P(Ph)CH2N(2-pyridyl)CH2], ring is found in a crown conformation while its cis-Mo(CO)(4) complex adopts a chair-boat ligand conformation. On the other hand, the cis-PdCl2 complex of [P(Ph)CH2N(Bz)CH2](2) is found to retain a highly flattened crown ligand conformation Unlike rha related eight-membered heterocycle 1,3,5,7-tetraoxa-2,3,6,8-tetraphosphacyclooctane which behaves as a tetradentate ligand chelating homo- or hetero-bimetallics, coordination to a second metal by these complexes was not realized. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00413-6

文献信息

• Complexes of cyclic aminomethylphosphines with Pt(II), Pd(II), Cu(I), and Ag(I) salts
  作者：B. A. Arbuzov、A. A. Karasik、G. N. Nikonov、E. V. Malova、R. Sh. Khadiullin、A. Kh. Plyamovatyi、K. M. Enikeev

  DOI：10.1007/bf00869510

  日期：1992.2

  1,3,5-Diazaphosphorinanes and 1,5,3,7-diazadiphosphacyclooctanes form complexes with Pt(II), Pd(II), Cu(I), and Ag(I) salts. Platinum and palladium are coordinated through phosphorous atoms. In the case of 1,3-diphenyl-5-p-toluidenomethyl-1,3,5-diazaphosphorinane complex formation with platinum and palladium is accompanied by formation of a new polydentate ligand, p-tolylbis-(1,3-di-p-tolyl-1,3,5-diazaphosphorinane-5-yl)methylamine, where the metal is also bonded to phosphorus atoms.