[3,5-Bis[[3,5-bis[(4-methoxycarbonylphenyl)methoxy]phenyl]methoxy]phenyl]methyl pyridine-4-carboxylate | 354145-86-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [3,5-Bis[[3,5-bis[(4-methoxycarbonylphenyl)methoxy]phenyl]methoxy]phenyl]methyl pyridine-4-carboxylate
• 英文别名: [3,5-bis[[3,5-bis[(4-methoxycarbonylphenyl)methoxy]phenyl]methoxy]phenyl]methyl pyridine-4-carboxylate
• CAS: 354145-86-1
• 化学式: C₆₃H₅₅NO₁₆
• 分子量: 1082.13
• InChiKey: YRZWXPYLZFTLIE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.4
• 重原子数：
  80
• 可旋转键数：
  30
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  200
• 氢给体数：
  0
• 氢受体数：
  17

反应信息

• 作为反应物：
  描述：

  、 [3,5-Bis[[3,5-bis[(4-methoxycarbonylphenyl)methoxy]phenyl]methoxy]phenyl]methyl pyridine-4-carboxylate 、 silver tetrafluoroborate 在 MeCN 作用下， 以 二氯甲烷 、 水 为溶剂， 生成
  参考文献：
  名称：

  Chemistry on Surface-Confined Molecules:  An Approach to Anchor Isolated Functional Units to Surfaces

  摘要：

  The synthesis of surface-confined, nanometer-sized dendrimers and Au nanoparticles was performed starting from single Pd-II pincer adsorbate molecules (10) embedded as isolated species into 11-mercapto-1-undecanol and decanethiol self-assembled monolayers (SAMs) on gold. The coordination of monolayer-protected Au nanoclusters (MPCs) bearing phosphine moieties at the periphery (13), or dendritic wedges (8) having a phosphine group at the focal point, to SAMs containing individual Pd-II pincer molecules was monitored by tapping mode atomic force microscopy (TM AFM). The individual Pd-II pincer molecules embedded in the decanethiol SAM were visualized by their coordination to phosphine MPCs 13; isolated objects with a height of 3.5 +/- 0.7 nm were observed by TM AFM. Reaction of these embedded Pd-II pincer molecules with the dendritic wedge 8 yielded individual molecules with a height of 4.3 +/- 0.2 nm.

  DOI：

  10.1021/ja010257c
• 作为产物：
  描述：

  氯化异氰盐酸盐 、 3,5-bis(3,5-bis(4-methoxycarbonylphenyl)benzyloxy)benzyl alcohol 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 8.0h， 以62%的产率得到[3,5-Bis[[3,5-bis[(4-methoxycarbonylphenyl)methoxy]phenyl]methoxy]phenyl]methyl pyridine-4-carboxylate
  参考文献：
  名称：

  Chemistry on Surface-Confined Molecules:  An Approach to Anchor Isolated Functional Units to Surfaces

  摘要：

  The synthesis of surface-confined, nanometer-sized dendrimers and Au nanoparticles was performed starting from single Pd-II pincer adsorbate molecules (10) embedded as isolated species into 11-mercapto-1-undecanol and decanethiol self-assembled monolayers (SAMs) on gold. The coordination of monolayer-protected Au nanoclusters (MPCs) bearing phosphine moieties at the periphery (13), or dendritic wedges (8) having a phosphine group at the focal point, to SAMs containing individual Pd-II pincer molecules was monitored by tapping mode atomic force microscopy (TM AFM). The individual Pd-II pincer molecules embedded in the decanethiol SAM were visualized by their coordination to phosphine MPCs 13; isolated objects with a height of 3.5 +/- 0.7 nm were observed by TM AFM. Reaction of these embedded Pd-II pincer molecules with the dendritic wedge 8 yielded individual molecules with a height of 4.3 +/- 0.2 nm.

  DOI：

  10.1021/ja010257c

文献信息

• Chemistry on Surface-Confined Molecules:  An Approach to Anchor Isolated Functional Units to Surfaces
  作者：Arianna Friggeri、Henk-Jan van Manen、Tommaso Auletta、Xue-Mei Li、Szczepan Zapotoczny、Holger Schönherr、G. Julius Vancso、Jurriaan Huskens、Frank C. J. M. van Veggel、David N. Reinhoudt

  DOI：10.1021/ja010257c

  日期：2001.7.1

  The synthesis of surface-confined, nanometer-sized dendrimers and Au nanoparticles was performed starting from single Pd-II pincer adsorbate molecules (10) embedded as isolated species into 11-mercapto-1-undecanol and decanethiol self-assembled monolayers (SAMs) on gold. The coordination of monolayer-protected Au nanoclusters (MPCs) bearing phosphine moieties at the periphery (13), or dendritic wedges (8) having a phosphine group at the focal point, to SAMs containing individual Pd-II pincer molecules was monitored by tapping mode atomic force microscopy (TM AFM). The individual Pd-II pincer molecules embedded in the decanethiol SAM were visualized by their coordination to phosphine MPCs 13; isolated objects with a height of 3.5 +/- 0.7 nm were observed by TM AFM. Reaction of these embedded Pd-II pincer molecules with the dendritic wedge 8 yielded individual molecules with a height of 4.3 +/- 0.2 nm.