| 189205-12-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 189205-12-7
• 化学式: C₂₇H₂₁CdCl₂N₅O₈
• 分子量: 726.808
• InChiKey: GNXCMHRNMNJAOT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium perchlorate 、 cadmium(II) acetate dihydrate 、 6,6''''-dimethyl-2,2':6',2'':6'',2''':6''',2''''-quinquepyridine 以 甲醇 为溶剂， 以91%的产率得到
  参考文献：
  名称：

  The double helical binuclear cooper complex of 6,6⁗ dimethyl-4′, 4‴ diphenyl-quinquepyridine and monohelical cadmium complex of 6,6⁗-dimethylquinquepyridine. Syntheses, crystal and molecular structure of [Cu2 (L2)2] [ClO4]3 · 2CH3CN and [CdL1] [ClO4]2

  摘要：

  The binuclear copper complex of 6,6''''-dimethyl-4',4'''-diphenylquinquepyridine L(2) and the mononuclear cadmium complex of 6,6''''-dimethyl-quinquepyridine L(1) have been prepared by the reaction of L(2) with Cu(ClO4)(2) . 6H(2)O and L(1) with Cd(ClO4)(2) . 2H(2)O, respectively. These complexes were characterized by elemental analysis, IR, H-1 NMR and fast atom bombardment MS spectra. X-ray crystallographic measurement reveals that a Cu-I Cu-II mixed valence state copper complex is obtained, in which two ligand molecules self-organized around the Cu-I and Cu-II ions to form a double helical configuration. The cadmium complex is mononuclear, has a highly symmetrical configuration and may be regarded as a monohelical compound. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00511-6