| 444310-87-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 444310-87-6
• 化学式: C₅H₂N₂O₄*C₁₀H₈N₂*Co*H₂O
• 分子量: 387.277
• InChiKey: LJULXHUZFZWAKL-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 cobalt(II) diacetate tetrahydrate 、 乳清酸 以 水 为溶剂， 以41%的产率得到
  参考文献：
  名称：

  Hydrothermal crystallisation of metal (II) orotates (M=nickel, cobalt, manganese or zinc). Effect of 2,2-bipyridyl, 2,2-dipyridyl amine, 1-methyl-3-(2-pyridyl)pyrazole, phenanthroline and 2,9-dimethyl-1,10-phenanthroline upon structure

  摘要：

  Hydrothermal synthesis of orotic acid (H3L) with Ni(OAc)(2) (.) 4H(2)O gives a green ID co-ordinative network of composition [Ni(HL)(H2O)(3)] (3). The kinetic product [Ni(HL) (.) (H2O)]H2O (4) can be prepared by conventional crystallisation. When boiled in water it is transformed into the thermodynamically favoured trihydrate 3. An unstable blue phase 5 that could not be characterised was also observed. Hydrothermal synthesis of orotic acid and M(OAc)(2) (.) 4H(2)O (M = Ni, Co, Mn or Zn) and either 2,2-bipyridyl (bipy), 2,2-dipyridylamine (dpa), phenanthroline (phen), methyl-3-(2-pyridyl)pyrazole (pypz) or 2,9-dimethyl-1,10-phenanthroline (dmphen) gave infinite 1D co-ordinative networks of composition [M(HL)bipy(H2O)] (M = Co or Mn) (6-7) and complexes of composition [Ni(HL)bipy (H2O)(2)]2H(2)O (8); [Ni(HL)(dpa)(H2O)(2)]H2O (9); [Ni(HL)(phen)(H2O2)](.)2H(2)O (10); [Ni(HL)(C9H9N3)(H2O)(2)](.)2H(2)O (11); [Ni(HL)(dmphen)(H2O)] (12); [Zn(HL)bipy(H2O)] (13) and [Ni(HL)(dpa)(2)](H2O)-H-. (14). (C) 2002 Published by Elsevier Science B.V.

  DOI：

  10.1016/s0020-1693(02)00728-4