6-chloro-4-methyl-benzo[b]thiophene | 220714-42-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻吩类
• 英文名称: 6-chloro-4-methyl-benzo[b]thiophene
• 英文别名: 6-Chlor-4-methyl-benzo[b]thiophen；6-Chloro-4-methyl-1-benzothiophene
• CAS: 220714-42-1
• 化学式: C₉H₇ClS
• 分子量: 182.674
• InChiKey: DBAQTXHKRRAQBY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  6-chloro-4-methyl-benzo[b]thiophene 在 三氯化铝 、 氯化亚砜 、 硝基苯 作用下， 生成 3-chloro-1-methyl-benzo[b]naphtho[2,3-d]thiophene-6,11-quinone
  参考文献：
  名称：

  Mayer, Justus Liebigs Annalen der Chemie, 1931, vol. 488, p. 259,275

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 生成 6-chloro-4-methyl-benzo[b]thiophene
  参考文献：
  名称：

  DE499745

  摘要：

  公开号：

文献信息

• LIQUID CRYSTAL COMPOSITION
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20170335191A1

  公开（公告）日：2017-11-23

  A liquid crystal composition which prevents production of an alignment defect of a liquid crystal compound and also has excellent storage stability during dissolution in a solvent is provided. The liquid crystal composition is suitable for constituting a retardation film capable of favorable circular polarization conversion. The liquid crystal composition includes a polymerizable liquid crystal compound having 3 or more ring structures in the main chain, and aluminum. A content of the aluminum is 1 ppm or more and 170 ppm or less relative to the polymerizable liquid crystal compound.

  提供了一种液晶组合物，可以防止液晶化合物的对准缺陷产生，并且在溶剂中溶解时具有优异的储存稳定性。该液晶组合物适用于构成具有良好圆偏振转换的减速膜。该液晶组合物包括具有3个或更多环结构的可聚合液晶化合物和铝。铝的含量相对于可聚合液晶化合物为1 ppm或更多，170 ppm或更少。
• Liquid crystal composition
  申请人：Sumitomo Chemical Company, Limited

  公开号：US10336938B2

  公开（公告）日：2019-07-02

  A liquid crystal composition containing a polymerizable liquid crystal compound (A) having 5 or more ring structures in its main chain and a polymer (B) of the polymerizable liquid crystal compound (A) having 5 or more ring structures in its main chain, which inhibits occurrence of an orientation defect of a liquid crystal compound and exhibits excellent storage stability when dissolved in a solvent is provided.

  本发明提供了一种液晶组合物，其中含有主链上具有 5 个或更多环状结构的可聚合液晶化合物（A）和主链上具有 5 个或更多环状结构的可聚合液晶化合物（A）的聚合物（B），该组合物能抑制液晶化合物取向缺陷的发生，并在溶解于溶剂中时表现出优异的储存稳定性。
• Liquid crystal composition, method of producing the same, and retardation film constituted from the same
  申请人：Sumitomo Chemical Company, Limited

  公开号：US11193065B2

  公开（公告）日：2021-12-07

  A liquid crystal composition is provided containing a polymerizable liquid crystal compound, the composition having high preservation stability when dissolved in a solvent and also having the ability to restrain the development of orientation defects of the liquid crystal compound. A method of producing such a liquid crystal composition is also provided with ease. The liquid crystal composition includes a first polymerizable liquid crystal compound having five or more ring structures on its principal chain and represented by the following formula (A) and a second polymerizable liquid crystal compound having five or more ring structures and represented by the following formula (B).

  提供了一种含有可聚合液晶化合物的液晶组合物，该组合物溶解在溶剂中时具有很高的保存稳定性，还能抑制液晶化合物取向缺陷的发展。此外，还提供了一种生产这种液晶组合物的简便方法。该液晶组合物包括主链上具有五个或五个以上环结构并由下式（A）表示的第一种可聚合液晶化合物和具有五个或五个以上环结构并由下式（B）表示的第二种可聚合液晶化合物。
• Process for production of heteroaryl-type boron compounds with iridium catalyst
  申请人：Miyaura Norio

  公开号：US20050148775A1

  公开（公告）日：2005-07-07

  The present invention provides an economically and industrially superior simple process that enables the selective production of an aromatic heterocyclic monoboron compound and aromatic heterocyclic diboron compound at a satisfactory yield and in a desired ratio by reacting an aromatic heterocyclic compound and a boron compound in a single step under mild conditions while changing only the charged ratios of the raw materials. The present invention provides a production process of a heteroaryl mono- or diboron compound comprising an aromatic heterocyclic compound and a boron compound in the form of bis(pinacolate)diboron or pinacolate diborane in the presence of a iridium-containing catalyst and a ligand such as a bipyridyl ligand.

  本发明提供了一种经济上和工业上优越的简单工艺，通过在温和条件下使芳香杂环化合物和硼化合物进行单步反应，同时仅改变原料的带电比例，就能以满意的产率和所需的比例选择性地生产芳香杂环单硼化合物和芳香杂环二硼化合物。本发明提供了一种杂芳基单硼或二硼化合物的生产工艺，该工艺由芳香杂环化合物和双(频哪醇)二硼或频哪醇二硼烷形式的硼化合物在含铱催化剂和配体如双吡啶配体的存在下组成。
• PROCESS FOR PRODUCTION OF HETEROARYL-TYPE BORON COMPOUNDS WITH IRIDIUM CATALYST
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：EP1481978B1

  公开（公告）日：2011-09-14