N-phenyl-4,4'-bipyridylium cation | 124948-23-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: N-phenyl-4,4'-bipyridylium cation
• 英文别名: 1-Phenyl-4-pyridin-4-ylpyridin-1-ium
• CAS: 124948-23-8
• 化学式: C₁₆H₁₃N₂
• 分子量: 233.293
• InChiKey: FWMMSEJKDWKWAU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  16.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-phenyl-4,4'-bipyridylium cation 在 锌 作用下， 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Clack, Dennis W.; Evans, Jeffrey C.; Morris, Caroline R., Journal of the Chemical Society. Perkin transactions II, 1988, p. 1541 - 1546

  摘要：

  DOI：

文献信息

• METHOD OF MANUFACTURING BIPYRIDINIUM COMPOUND AND SYNTHETIC INTERMEDIATE OF THE SAME, METHOD OF MANUFACTURING DYE COMPOUND, AND NOVEL BIPYRIDINIUM COMPOUND AND NOVEL DYE COMPOUND COMPRISING THE SAME
  申请人：Nii Kazumi

  公开号：US20090082570A1

  公开（公告）日：2009-03-26

  Provided is a method of manufacturing a bipyridinium compound denoted by general formula (A). In general formula (A), Ar 1 and Ar 2 each independently denote an optionally substituted (hetero)aryl group, R 3 and R 4 each independently denote a substituent that may form a ring with a pyridine ring to which the substituent substitutes, m3 and m4 each independently denote an integer ranging from 0 to 4, X denotes a halogen atom or RSO 3 , and R denotes an optionally substituted aryl group or alkyl group. The method can manufacture a 4,4′-bipyridinium compound under mild reaction conditions in an integrated manner without separation of intermediates.

  提供了一种制造双吡啶化合物的方法，其通用式为(A)。在通用式(A)中，Ar1和Ar2分别独立表示可选择取代的(杂)芳基团，R3和R4分别独立表示可与取代基形成环的基团，m3和m4分别独立表示范围从0到4的整数，X表示卤原子或RSO3，R表示可选择取代的芳基团或烷基团。该方法可以在温和的反应条件下以一体化方式制造4,4'-双吡啶化合物，无需中间体的分离。
• CATIONIC COMPOUND, DYE COMPOUND AND METHOD OF USING THE SAME, AND OPTICAL INFORMATION RECORDING MEDIUM
  申请人：Nii Kazumi

  公开号：US20090130367A1

  公开（公告）日：2009-05-21

  The present invention relates to a cationic compound denoted by the general formula (I). In general formula (I), Ar 1 and Ar 2 each independently denote an optionally substituted aryl group or aromatic heterocyclic group, L 1 denotes a single bond or a divalent linkage group, with at least one from among Ar 1 , Ar 2 and L 1 comprising one or more onium cations; R 3 and R 4 each independently denote a substituent and may form a ring with a benzene ring substituted; m3 and m4 each independently denote an integer ranging from 0 to 4, and plural R 3 s and R 4 s may be identical or different from each other when m3 and m4 are an integer ranging from 2 to 4.

  本发明涉及一种由一般式（I）表示的阳离子化合物。在一般式（I）中，Ar1和Ar2各自独立地表示可选取代的芳基或芳香杂环基团，L1表示单键或二价连接基团，其中至少有一个来自于Ar1、Ar2和L1中的一个或多个离子上阳离子；R3和R4各自表示取代基团，并且可以与苯环取代形成环；m3和m4各自独立地表示从0到4的整数，当m3和m4为从2到4的整数时，复数的R3和R4可能相同也可能不同。
• The assignment of the hyperfine coupling constants of asymmetrical n,n'-diaryl-; n,n'-dialkyl-; and n-alkyl-n'-aryl-4,4'-bipyridylium radical cations
  作者：Jeffrey C. Evans、Caroline R. Morris、Christopher C. Rowlands

  DOI：10.1016/s0040-4020(01)87710-3

  日期：1987.1

  ESR and multiple resonance spectra were obtained for the radical cations of asymmetrical diquaternary 4,4'-bipyridylium compounds in which alkyl and aryl quaternising groups occur in a mixed fashion. The effect of these groups on the bipyridylium protons has shown clear trends which are used to predict the assignment for positions which cannot readily be deuterated.

  对于其中烷基和芳基季铵化基团以混合方式出现的不对称双季铵4,4'-联吡啶鎓化合物的自由基阳离子，获得了ESR和多重共振谱。这些基团对联吡啶质子的影响已显示出明显的趋势，这些趋势可用于预测不容易氘化的位置的分配。
• ELECTROCHROMIC ELEMENT
  申请人：Nippon Mitsubishi Oil Corporation

  公开号：EP1154311A9

  公开（公告）日：2009-03-11

  An electrochromic element comprises an ion conduction layer between two conducting substrates, at least one of which is transparent. The ion conduction layer contains an organic compound, which has both a structure exhibiting a cathodic electrochromic characteristic and a structure exhibiting an anodic electrochromic characteristic.

  电致变色元件包括两个导电基底之间的离子传导层，其中至少有一个基底是透明的。离子传导层中含有一种有机化合物，其结构既具有阴极电致变色特性，又具有阳极电致变色特性。
• CATION COMPOUND, DYE COMPOUND AND USE THEREOF, AND OPTICAL INFORMATION RECORDING MEDIUM
  申请人：FUJIFILM Corporation

  公开号：EP1950255A1

  公开（公告）日：2008-07-30

  The present invention relates to a cationic compound denoted by the general formula (I). In general formula (I), Ar1 and Ar2 each independently denote an optionally substituted aryl group or aromatic heterocyclic group, L1 denotes a single bond or a divalent linkage group, with at least one from among Ar1, Ar2 and L1 comprising one or more onium cations; R3 and R4 each independently denote a substituent and may form a ring with a benzene ring substituted; m3 and m4 each independently denote an integer ranging from 0 to 4, and plural R3s and R4s may be identical or different from each other when m3 and m4 are an integer ranging from 2 to 4.

  本发明涉及通式（I）表示的阳离子化合物。在通式（I）中，Ar1 和 Ar2 各自独立地表示任选取代的芳基或芳香杂环基团，L1 表示单键或二价连接基团，Ar1、Ar2 和 L1 中至少有一个包含一个或多个鎓阳离子；R3和R4各自独立地表示一个取代基，并可与被取代的苯环形成一个环；m3和m4各自独立地表示0至4的整数，当m3和m4为2至4的整数时，多个R3s和R4s可彼此相同或不同。