Electrochemical synthesis, structure, magnetic and tribochemical properties of metallochelates of new azomethine ligands, bis-[2-(N-tosylaminobenzylidenealkyl(aryl)]disulfides
作者:A. S. Burlov、S. A. Mashchenko、O. A. Ivashchenko、D. A. Garnovskii、A. I. Uraev、M. S. Korobov、I. G. Borodkina、G. G. Chigarenko、A. G. Ponomarenko、A. D. Garnovskii
DOI:10.1134/s1070363209030128
日期:2009.3
On the basis of new ligand systems, bis-azomethines of N-tosylaminobenzaldehyde and alkyl(aryl)diaminodisulfides, mono- and binuclear chelates with 4N- and 2N2S-ligand arrangement were chemically (from metal acetates) or electrochemically (from metals in the zero oxidation state) first synthesized and characterized. Mononuclear chelates have a tetrahedral structure. In binuclear copper complexes the magnetic exchange interaction of the antiferromagnetic type was observed. Bisazomethines of disulfides were used as additives to lubricant oils.