N-phenyl-4-[α-(diethylphosphoryl)benzylamino]naphthalimide | 1128246-31-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: N-phenyl-4-[α-(diethylphosphoryl)benzylamino]naphthalimide
• CAS: 1128246-31-0
• 化学式: C₂₉H₂₇N₂O₅P
• 分子量: 514.518
• InChiKey: ZVXIZVPZFGYDHI-UHFFFAOYSA-N

物化性质

• 熔点：
  258-259 °C
• 沸点：
  718.7±60.0 °C(predicted)
• 密度：
  1.337±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.02
• 重原子数：
  37.0
• 可旋转键数：
  9.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  84.94
• 氢给体数：
  1.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  4-aminonaphthalic acid phenylimide 、 苯甲醛 、 亚磷酸二乙酯 反应 2.0h， 以76.3%的产率得到N-phenyl-4-[α-(diethylphosphoryl)benzylamino]naphthalimide
  参考文献：
  名称：

  Synthesis and investigation of new organophosphorus dyes of green and red luminescence

  摘要：

  On the basis of amino derivatives of N-phenylnaphthalimide, naphthoylenebenzimidazole, benzanthrone, and phenalenone new phosphorus-containing luminophores containing phosphonomethyl and phosphazo groups in their structures were synthesized. Luminiscence spectrum and excitation characteristics of compounds obtained were studied. Some of the synthesized substances were proposed for application as effective laser dyes for green and red spectral regions with a wide range of retuning.

  DOI：

  10.1134/s1070363208030080