4-(Dimethylamino)-1-pentene | 77118-00-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-(Dimethylamino)-1-pentene
• 英文别名: N,N-dimethylpent-en-4-ylamine；N,N-dimethylpent-4-en-2-amine
• CAS: 77118-00-4
• 化学式: C₇H₁₅N
• 分子量: 113.203
• InChiKey: AWVMCKBHHQPKEW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  sodium methylate 、 cis-1,1,2,4-Tetramethylazetidinium perchlorate 以 甲醇 为溶剂， 生成 丁烯 、 顺-2-丁烯 、 反-2-丁烯 、 N,N-二甲基-2-丁胺 、 4-(Dimethylamino)-2-pentyl Methyl Ether 、 4-(Dimethylamino)-1-pentene
  参考文献：
  名称：

  Ring-opening reactions. 3. Mechanistic path vs. ring-strain control in elimination and substitution reactions of 1,1-dimethyl cyclic ammonium ions and their .alpha.,.alpha.'-dimethyl-substituted derivatives

  摘要：

  DOI：

  10.1021/jo00327a021

文献信息

• Catalyst for the Conversion of Syngas to Olefins and Preparation Thereof
  申请人：BASF SE

  公开号：US20140113981A1

  公开（公告）日：2014-04-24

  Described is a process for the production of a pillared silicate. The process comprises (i) providing a layered silicate; (ii) interlayer expanding the layered silicate provided in step (i) comprising a step of treating the layered silicate with one or more swelling agents; (iii) treating the interlayer expanded silicate obtained in step (ii) with one or more hydrolyzable silicon containing compounds; (iv) treating the interlayer expanded compound obtained in step (iii) with an aqueous solution to obtain a pillared silicate; (v) removing at least a portion of the one or more swelling agents from the pillared silicate obtained in step (iv); and (vi) impregnating the pillared silicate obtained in step (v) with one or more elements selected from the group consisting of Fe, Ru, Ir, and combinations of two or more thereof. Also described is a pillared silicate optionally obtainable from said process and its use, in particular, in a process for the production of one or more olefins according to the invention.

  描述了一种生产柱撑硅酸盐的过程。该过程包括：(i) 提供一种层状硅酸盐；(ii) 对步骤(i)提供的层状硅酸盐进行层间膨胀，包括用一种或多种膨胀剂处理层状硅酸盐的步骤；(iii) 用一种或多种可水解硅含化合物处理步骤(ii)得到的层间膨胀硅酸盐；(iv) 用水溶液处理步骤(iii)得到的层间膨胀化合物以获得柱撑硅酸盐；(v) 从步骤(iv)得到的柱撑硅酸盐中去除至少一部分膨胀剂；(vi) 用选自Fe、Ru、Ir和两种或更多元素的组合的一种或多种元素浸渍步骤(v)得到的柱撑硅酸盐。还描述了一种可选从该过程中获得的柱撑硅酸盐及其用途，特别是在根据本发明生产一种或多种烯烃的过程中的用途。
• GEL POLYMER ELECTROLYTE COMPOSITION
  申请人：Kuraray Co., Ltd.

  公开号：EP2524932A1

  公开（公告）日：2012-11-21

  An objective of the present invention is to provide a gel polymer electrolyte composition which exhibits excellent electrolyte retaining ability, excellent ion conductivity, higher mechanical strength and excellent shape preservation, which does not require an extra step for crosslinking, and which can provide a secondary battery with excellent cycle properties and a vinyl acetal polymer used for a gel polymer electrolyte composition. There are provided a vinyl acetal polymer for a gel polymer electrolyte composition, wherein the vinyl acetal polymer has a cationic functional group, as well as a gel polymer electrolyte composition comprising the vinyl acetal polymer and an electrolyte solution, wherein a weight ratio of the vinyl acetal polymer to the electrolyte solution is 0.5:99.5 to 9:91.

  本发明的目的是提供一种凝胶聚合物电解质组合物，该组合物具有优异的电解质保持能力、优异的离子传导性、较高的机械强度和优异的形状保持性，不需要额外的交联步骤，可提供具有优异循环性能的二次电池，以及一种用于凝胶聚合物电解质组合物的乙缩醛聚合物。提供了一种用于凝胶聚合物电解质组合物的乙烯基乙缩醛聚合物，其中乙烯基乙缩醛聚合物具有阳离子官能团，以及一种凝胶聚合物电解质组合物，该组合物由乙烯基乙缩醛聚合物和电解质溶液组成，其中乙烯基乙缩醛聚合物与电解质溶液的重量比为 0.5:99.5 至 9:91。
• Method for preparing antistatic expandable polystyrene
  申请人：ARCO Chemical Technology, L.P.

  公开号：EP0289321B1

  公开（公告）日：1992-11-11
• EP2909142A2
  申请人：——

  公开号：EP2909142A2

  公开（公告）日：2015-08-26
• UV-ABSORBING POLYMERS AND FORMULATIONS THEREOF
  申请人：ISP INVESTMENTS LLC

  公开号：US20170114173A1

  公开（公告）日：2017-04-27

  UV-absorbing polymers are provided that have at least one anhydride repeating unit that is covalently attached to at least one UV-absorbing moiety selected from the group consisting of functionalized dibenzoylmethanes, benzophenone sulfonamides, triphenyl triazines, and combinations thereof. Also provided are formulations comprising the UV-absorbing polymers.