hexa(propylsulfonyl)phthalocyaninatonickel(II)-[2.2]paracyclophane | 609337-86-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: hexa(propylsulfonyl)phthalocyaninatonickel(II)-[2.2]paracyclophane
• CAS: 609337-86-2
• 化学式: C₆₈H₆₈N₈NiO₁₂S₆
• 分子量: 1440.42
• InChiKey: QXEFRPGHEZXHCE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-vinyl[2.2]paracyclophane 、 24-Iodo-6,7,15,16,33,34-hexakis(propylsulfonyl)-2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1(37),2,4,6,8,10,12(39),13,15,17,19,21,23,25,27,29,31,33,35-nonadecaene;nickel(2+) 在 (C₂H₅)2((CH₃)2CH)N 、 tetra-n-butylammonium bromide 、 Pd(CH₃CN)2Cl₂ 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以37%的产率得到hexa(propylsulfonyl)phthalocyaninatonickel(II)-[2.2]paracyclophane
  参考文献：
  名称：

  Donor−Acceptor Phthalocyanine Nanoaggregates

  摘要：

  A novel donor-acceptor bisphthalocyanine (bis-Pc, 1) in which two different PC units (Zn(II)-Pc and Ni(II)-Pc) are linked via vinylene spacers to the pseudopara positions of a central [2.2]paracyclophane moiety is described. The synthesis of 1 is achieved by two successive Heck reactions of pseudopara-divinyl[2.2]paracyclophane 9 with, sequentially, a zinc(II)- and a nickel(II)-iodophthalocyanine (4 and 5, respectively). The self-assembly ability of 1, which is the result of the complementary donor-acceptor character of its phthalocyanine units, has been assessed by a variety of techniques. It is revealed that 1 forms one-dimensional aggregates of nanometer-sized dimension, whereas equimolar mixtures of the donor and acceptor PC subunits 2 and 3, although strongly interacting, do not give large arrays. The aggregates of 1 represent a novel type of supramolecular polymers based mainly upon donor-acceptor interactions.

  DOI：

  10.1021/ja030038m