Bis[(pyridin-2-yl)methyl] benzene-1,4-dicarboxylate | 828915-35-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Bis[(pyridin-2-yl)methyl] benzene-1,4-dicarboxylate
• 英文别名: bis(pyridin-2-ylmethyl) benzene-1,4-dicarboxylate
• CAS: 828915-35-1
• 化学式: C₂₀H₁₆N₂O₄
• 分子量: 348.358
• InChiKey: RKSULSNXBAJLMV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  26
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  78.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  Bis[(pyridin-2-yl)methyl] benzene-1,4-dicarboxylate 、 水 、 silver trifluoromethanesulfonate 以 乙腈 为溶剂， 以28%的产率得到
  参考文献：
  名称：

  Helical metallopolymers from the coordination of new bis(pyridyl)terephthalate ligands with silver(I)

  摘要：

  Two new bis(pyridyl)terephthalate ligands were synthesized in good yields from the reaction of either 2-pyridylcarbinol or 2-pyridinepropanol with terephthaloyl chloride in the presence of triethylamine. Mixing these ligands with silver(I) salts resulted in the formation of crystalline helical polymeric complexes. In the complexation involving silver triflate, two separate structures were obtained, one of which contained water in the asymmetric unit. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2004.07.005

文献信息

• Helical metallopolymers from the coordination of new bis(pyridyl)terephthalate ligands with silver(I)
  作者：Mananjali K. Kalra、Hongming Zhang、David Y. Son

  DOI：10.1016/j.inoche.2004.07.005

  日期：2004.9

  Two new bis(pyridyl)terephthalate ligands were synthesized in good yields from the reaction of either 2-pyridylcarbinol or 2-pyridinepropanol with terephthaloyl chloride in the presence of triethylamine. Mixing these ligands with silver(I) salts resulted in the formation of crystalline helical polymeric complexes. In the complexation involving silver triflate, two separate structures were obtained, one of which contained water in the asymmetric unit. (C) 2004 Elsevier B.V. All rights reserved.