1,1'-([1,1'-biphenyl]-4,4'-diylbis(oxy))bis(N,N,N',N'-tetraethylphosphanediamine) | 863650-10-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,1'-([1,1'-biphenyl]-4,4'-diylbis(oxy))bis(N,N,N',N'-tetraethylphosphanediamine)
• CAS: 863650-10-6
• 化学式: C₂₈H₄₈N₄O₂P₂
• 分子量: 534.662
• InChiKey: ZDXUXTJODHHGBK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.93
• 重原子数：
  36.0
• 可旋转键数：
  17.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  31.42
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  1,1'-([1,1'-biphenyl]-4,4'-diylbis(oxy))bis(N,N,N',N'-tetraethylphosphanediamine) 在 sulfur 作用下， 以 乙腈 为溶剂， 反应 2.0h， 以0.41 g的产率得到biphenyl-4,4'-diyl bis(tetraethylphosphorodiamidothioate-O)
  参考文献：
  名称：

  摘要：

  The first representatives of linear phosphocyclophanes were prepared starting from hydroquinone or 4,4'-dihydroxybiphenyl and phosphorous triamides. The reaction course is influenced by the structures of the aromatic diol and alkyl substituents in the phosphamide moiety. The phosphorus atom readily enters redox reactions and complexation. The complexing power of the aromatic fragments of the synthesized molecules is lower than that of classical p-cyclophanes.

  DOI：

  10.1023/a:1012357001662
• 作为产物：
  描述：

  4,4'-二羟基联苯 、 六乙基亚磷酸胺 以 乙腈 为溶剂， 反应 1.67h， 生成 1,1'-([1,1'-biphenyl]-4,4'-diylbis(oxy))bis(N,N,N',N'-tetraethylphosphanediamine)
  参考文献：
  名称：

  摘要：

  The first representatives of linear phosphocyclophanes were prepared starting from hydroquinone or 4,4'-dihydroxybiphenyl and phosphorous triamides. The reaction course is influenced by the structures of the aromatic diol and alkyl substituents in the phosphamide moiety. The phosphorus atom readily enters redox reactions and complexation. The complexing power of the aromatic fragments of the synthesized molecules is lower than that of classical p-cyclophanes.

  DOI：

  10.1023/a:1012357001662

文献信息

• Dismutation of arylene phosphorodiamidites: Specific features and aspects of preparative use
  作者：E. N. Rasadkina、P. V. Slitikov、E. E. Nifant’ev

  DOI：10.1134/s1070363206020046

  日期：2006.2

  The dismutation ofarylene phosphorodiamidites derived from the simplest phenols and naphthols and of their dibasic analogs was studied. The main regular trends of this process and the limits of its synthetic applicability were determined.