1-(4-N-methylaminophenyl)-2-phenyl-1,2-dicarba-closo-dodecaborane | 490041-02-6

• 英文名称: 1-(4-N-methylaminophenyl)-2-phenyl-1,2-dicarba-closo-dodecaborane
• CAS: 490041-02-6
• 化学式: C₁₅H₂₃B₁₀N
• 分子量: 325.464
• InChiKey: KUHUUBYNXAVGKO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1-(4-N-methylaminophenyl)-2-phenyl-1,2-dicarba-closo-dodecaborane 、 N-甲基-N-苯基氨基甲酰氯 在 triethylamine 作用下， 以 1,2-二氯乙烷 为溶剂， 以76%的产率得到
  参考文献：
  名称：

  Molecular construction based on icosahedral carboranes and aromatic N,N′-dimethylurea groups. Aromatic layered molecules and a transition metal complex

  摘要：

  cis-Preference of N-methyl aromatic ureas in combination with regulation of the C-substituent on an o-carborane cage is applicable to construct structurally unique macromolecules. Aromatic ureas with multilayer structure (5-12) and an aromatic urea containing an intramolecular nido-carborane-cobalt complex (13) were synthesized and their structures were determined by X-ray crystallography. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01322-0
• 作为产物：
  描述：

  甲酸 、 硼烷四氢呋喃络合物 、 1-(4-aminophenyl)-2-phenyl-1,2-dicarba-closo-dodecaborane 在 Ac₂O 、 citric acid 作用下， 以 四氢呋喃 为溶剂， 以81%的产率得到1-(4-N-methylaminophenyl)-2-phenyl-1,2-dicarba-closo-dodecaborane
  参考文献：
  名称：

  Molecular construction based on icosahedral carboranes and aromatic N,N′-dimethylurea groups. Aromatic layered molecules and a transition metal complex

  摘要：

  cis-Preference of N-methyl aromatic ureas in combination with regulation of the C-substituent on an o-carborane cage is applicable to construct structurally unique macromolecules. Aromatic ureas with multilayer structure (5-12) and an aromatic urea containing an intramolecular nido-carborane-cobalt complex (13) were synthesized and their structures were determined by X-ray crystallography. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01322-0