[Zn(1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaoctane-1,8-diamine(-2H))] | 1094570-06-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Zn(1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaoctane-1,8-diamine(-2H))]
• CAS: 1094570-06-5
• 化学式: C₂₂H₂₄N₄O₆*Zn
• 分子量: 505.846
• InChiKey: RAEMYBVLTITLIX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.46
• 重原子数：
  33.0
• 可旋转键数：
  13.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  169.5
• 氢给体数：
  4.0
• 氢受体数：
  10.0

反应信息

• 作为反应物：
  描述：

  [Zn(1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaoctane-1,8-diamine(-2H))] 、 sodium perchlorate 、 水 、 copper diacetate 在 LiOH 作用下， 以 甲醇 、 水 为溶剂， 以70%的产率得到[CuZn(H2O)2(1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaoctane-1,8-diamine(-4H))]
  参考文献：
  名称：

  Synthesis, spectroscopic characterization and magnetic properties of homo- and heterodinuclear complexes of transition and non-transition metal ions with a new Schiff base ligand

  摘要：

  Four homodinuclear complexes of Ni(II)-Ni(II), Cu(II)-Cu(II), Co(II)-Co(II) and Co(III)-Co(II) and five heterodinuclear complexes of Co(III)-Zn(II), Co(III)-Cu(II), Co(III)-Ni(II), Cu(II)-Zn(II) and Zn(II)-Cu(II) with the octadentate Schiff base compartmental ligand 1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaoctane-1,8-diamine (H(4)fsatrien) have been synthesized. The complexes have been characterized with the help of elemental analyses, molecular weights, molar conductances, magnetic susceptibilities and spectroscopic (UV-vis, IR, ESR) data. Cryomagnetic data also helped to elucidate the structural features of the Cu(II) complexes. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2008.06.002