N-(4-bromophenyl)-N-(4-t-butyl-2,6-dimethylphenyl)-N-phenylamine | 916814-69-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(4-bromophenyl)-N-(4-t-butyl-2,6-dimethylphenyl)-N-phenylamine
• 英文别名: N-(4-bromophenyl)-4-tert-butyl-2,6-dimethyl-N-phenylaniline
• CAS: 916814-69-2
• 化学式: C₂₄H₂₆BrN
• 分子量: 408.381
• InChiKey: NDLZXNGWNWLRMY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  26
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-(4-bromophenyl)-N-(4-t-butyl-2,6-dimethylphenyl)-N-phenylamine 在 N-碘代丁二酰亚胺 、 三氟乙酸 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 5.0h， 以80%的产率得到N-(4-bromophenyl)-4-tert-butyl-N-(4-iodophenyl)-2,6-dimethylaniline
  参考文献：
  名称：

  WO2006/132357

  摘要：

  公开号：
• 作为产物：
  描述：

  N,N-bis(4-bromophenyl)-N-(4-t-butyl-2,6-dimethylphenyl)-amine 在 正丁基锂 、 水 作用下， 以 四氢呋喃 、 乙醚 、 正己烷 为溶剂， 反应 4.0h， 以40%的产率得到N-(4-bromophenyl)-N-(4-t-butyl-2,6-dimethylphenyl)-N-phenylamine
  参考文献：
  名称：

  WO2006/132357

  摘要：

  公开号：

文献信息

• Aromatic Graft Polymer
  申请人：Ohuchi Kazuei

  公开号：US20090096355A1

  公开（公告）日：2009-04-16

  An aromatic graft polymer containing one or more kinds of repeating units represented by the following formula (1). (In the formula, Ar 1 represents a divalent residue of a π-conjugated cyclic compound having a side chain represented by the following formula (2), the side chain being bonded to a carbon atom which is included in the ring structure of the divalent π-conjugated-cyclic-compound residue represented by Ar 1 and has an sp 2 hybrid orbital: (wherein Ar 2 represents a divalent group having a residue of a π-conjugated cyclic compound; X 1 represents a direct bond or a divalent group selected from the group consisting of NQ 1 -, —PQ 2 -, and —BQ 3 -, wherein Q 1 to Q 3 each independently represents a substituent; Z represents a direct bond or a divalent connecting group; k is an integer of 3 or larger; and E 1 represents hydrogen, halogeno, or a monovalent organic group, provided that when two or more Ar 2 's, X 1 's, and Z's are present, then they each may be the same or different and when two or more side chains represented by the formula (2) are present, then they may be the same or different.))

  含有由以下公式（1）所表示的一种或多种重复单元的芳香嫁接聚合物。（其中，Ar1表示具有以下公式（2）所表示的侧链的π-共轭环状化合物的二价残基，侧链与包括在由Ar1表示的二价π-共轭环状化合物残基的环结构中的碳原子结合，并具有sp2杂化轨道：（其中，Ar2表示具有π-共轭环状化合物残基的二价基团；X1表示直接键或从由NQ1-，-PQ2-和-BQ3-组成的二价基团中选择的基团，其中Q1到Q3各自独立地表示取代基；Z表示直接键或二价连接基团；k是大于等于3的整数；E1表示氢，卤素或一价有机基团，但当存在两个或更多的Ar2，X1和Z时，它们可以各自相同或不同，当存在两个或更多的由公式（2）表示的侧链时，则它们可以相同或不同。））
• Process for producing polymer
  申请人：Ohuchi Kazuei

  公开号：US20090209715A1

  公开（公告）日：2009-08-20

  A process for producing a polymer, characterized by comprising the following step (A) and step (B). (A) A step in which a polymer having repeating units represented by the general formula (1): —Ar 1 — (wherein Ar 1 represents an arylene, divalent heterocyclic, or divalent aromatic amine group having at least one C—H bond on the aromatic ring) is used as a raw material and one or more of the C—H bond(s) on the aromatic ring are converted to thereby produce a polymer having repeating units which have one or more characteristic groups X and are represented by the general formula (2): (wherein X represents a characteristic group; Ar 2 represents an arylene group, heterocyclic group, or aromatic amine group which each has a valence of n+2 and in each of which n of the C—H bonds on the aromatic ring of Ar 1 have been converted into a C—X bond; and n is an integer of 1-4) (hereinafter, this polymer is referred to as polymer having the characteristic group (X)). (B) A step in which the polymer having the characteristic group (X) produced in the step (A) is reacted with a compound having a characteristic group (Y) which reacts with the characteristic group (X) to form a bond.

  一种制备聚合物的方法，其特征在于包括以下步骤（A）和步骤（B）。 （A）使用具有由通式（1）表示的重复单元的聚合物作为原料，并将芳香环上的一个或多个C-H键转化，从而产生具有一个或多个特征基团X的重复单元的聚合物，该聚合物由通式（2）表示：（其中X表示特征基团；Ar2表示具有n+2价的芳香族、杂环族或芳香胺基团，其中每个基团的Ar1芳香环上的n个C-H键已转化为C-X键；n是1-4的整数）（以下简称具有特征基团（X）的聚合物）。 （B）将在步骤（A）中生产的具有特征基团（X）的聚合物与具有与特征基团（X）反应形成键的特征基团（Y）的化合物反应。
• AROMATIC POLYMER
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1892256A1

  公开（公告）日：2008-02-27

  Disclosed is an aromatic polymer containing one or more repeating units represented by the following formula (1). (In the formula, Ar1 represents an arylene group having a fused ring structure or a divalent heterocyclic compound group having a π-conjugated system, and contains a group represented by the formula (2) below. This group is bonded to a carbon atom having a sp2 hybrid orbital which is contained in a ring of the ring structure of the arylene group having a fused ring structure or the divalent heterocyclic compound group having a π-conjugated system represented by Ar1. (In the formula (2), E1 represents a hydrogen atom, a halogen atom or a monovalent organic group; Ar2 represents a group having a divalen-t π-conjugated cyclic compound residue, and two Ar2's may be the same as or different from each other; X1 represents a divalent group selected from the group consisting of -NQ1-, -PQ2- and -BQ3-, and Q1-Q3 independently represent a substituent; Z represents a direct bond or a divalent linking group, and two Z's may be the same as or different from each other; mi' s respectively represent 0 or 1; and in case where two X1's exist, they may be the same as or different from each other.)

  本发明公开了一种芳香族聚合物，该聚合物含有一个或多个由下式(1)表示的重复单元。(式中，Ar1 代表具有融合环结构的芳烯基团或具有π-共轭体系的二价杂环化合物基团，并含有下式（2）所代表的基团。该基团与具有 sp2 杂化轨道的碳原子键合，该碳原子包含在具有融合环结构的芳烯基团或具有 Ar1 所代表的 π 共轭体系的二价杂环化合物基团的环结构中。(在式 (2) 中，E1 代表氢原子、卤素原子或一价有机基团；Ar2 代表具有二价π-共轭环状化合物残基的基团，两个 Ar2 可以相同或不同；X1代表选自-NQ1-、-PQ2-和-BQ3-组成的组的二价基团，Q1-Q3独立地代表取代基；Z代表直接键或二价连接基团，两个Z可以相同或不同；mi's分别代表0或1；如果存在两个X1，它们可以相同或不同。)
• PROCESS FOR PRODUCING POLYMER
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1892258A1

  公开（公告）日：2008-02-27

  A process for producing a polymer, characterized by comprising the following step (A) and step (B). (A) A step in which a polymer having repeating units represented by the general formula (1): -Ar1- (wherein Ar1 represents an arylene, divalent heterocyclic, or divalent aromatic amine group having at least one C-H bond on the aromatic ring) is used as a raw material and one or more of the C-H bond(s) on the aromatic ring are converted to thereby produce a polymer having repeating units which have one or more characteristic groups X and are represented by the general formula (2): (wherein X represents a characteristic group; Ar2 represents an arylene group, heterocyclic group, or aromatic amine group which each has a valence of n+2 and in each of which n of the C-H bonds on the aromatic ring of Ar1 have been converted into a C-X bond; and n is an integer of 1-4) (hereinafter, this polymer is referred to as polymer having the characteristic group (X)). (B) A step in which the polymer having the characteristic group (X) produced in the step (A) is reacted with a compound having a characteristic group (Y) which reacts with the characteristic group (X) to form a bond.

  一种生产聚合物的工艺，其特征在于包括以下步骤(A)和步骤(B)。(A) 具有通式（1）所代表的重复单元的聚合物的步骤：-Ar1-（其中 Ar1 代表芳环上至少有一个 C-H 键的芳烯、二价杂环或二价芳香胺基团）的聚合物作为原料，并将芳环上的一个或多个 C-H 键转化，从而生产出具有重复单元的聚合物，该重复单元具有一个或多个特征基团 X，并由通式（2）表示：(其中 X 代表特征基团；Ar2 代表芳烯基团、杂环基团或芳香胺基团，它们各自的化合价为 n+2，其中 Ar1 的芳香环上的 n 个 C-H 键已转化为 C-X 键；n 为 1-4 的整数）（以下称这种聚合物为具有特征基团 (X) 的聚合物）。(B) 将步骤(A)中生产的具有特征基团(X)的聚合物与具有特征基团(Y)的化合物反应，后者与特征基团(X)反应形成键。
• NOVEL ARYL COMPOUND
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1892234A1

  公开（公告）日：2008-02-27

  A novel aryl compound represented by the formula (1) in which the characteristic groups represented by X1 and X2 are different from each other: wherein X1 and X2 are characteristic groups which are different from each other and each of which is selected from the group consisting of a chlorine, bromine or iodine atom, -OSO2Q1, -B(OQ2)2, -Si(OQ3)3, -Sn(Q4)3, Z1(Z2)m, a metal acetylide group and a terminal acetylene group (where Q represents a hydrocarbon group; Q2 represetns a hydrogen atom or a hydrocarbon gruop; two Q2's may be the same as or different from each other or may together form a ring; Q3 represents a hydrocarbon group and three Q3's may be the same as or different from one another; Q4 represetns a hydrocarbon group and three Q4's may be the same as different from one another; Z1 represents a metal atom or a metal ion; Z2 represents a counter anion; and m is an integer of 0 or higher); Ar1 and Ar2 independently represent an arylene group and Ar3 represetns an aryl group, provided that any two of Ar1, Ar2 and Ar3 may be bound to each other via a substituent or directly; Y represents a trivalent atomic group having a nitrogen, carbon, boron or silicon atom to which a hydrogen atom or a hydrocarbon group may be added if required; J represents an arylene group; and n is an integer of 0 or higher; provided that, when each of J, Y and Ar3 is present in the molecule in plural number, they may be the same as or different from each other or one another.

  一种由式（1）表示的新型芳基化合物，其中 X1 和 X2 所代表的特征基团互不相同： 其中 X1 和 X2 是互不相同的特征基团，每个特征基团选自由氯、溴或碘原子、-OSO2Q1、-B(OQ2)2、-Si(OQ3)3、-Sn(Q4)3、Z1(Z2)m、金属乙酰基和末端炔基（其中 Q 代表烃基；Q2 代表氢原子或烃基，两个 Q2 可以相同或不同，也可以共同形成一个环；Q3 代表烃基，三个 Q3 可以相同或不同；Q4 代表烃基，三个 Q4 可以相同或不同；Z1 代表金属原子或金属离子；Z2 代表反阴离子；m 为 0 或更大的整数）；Ar1 和 Ar2 独立地代表芳烯基团，Ar3 代表芳基，条件是 Ar1、Ar2 和 Ar3 中的任意两个可通过取代基相互结合或直接结合；Y 代表具有氮原子、碳原子、硼原子或硅原子的三价原子团，如有需要，可在其上添加氢原子或烃基团；J 代表芳烯基团；n 为 0 或更大的整数；条件是，当 J、Y 和 Ar3 以复数形式存在于分子中时，它们可以彼此相同或彼此不同。