(N-phenyl-2-pyridinamine)2dicobalt(II) tetraacetate | 439556-55-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: (N-phenyl-2-pyridinamine)2dicobalt(II) tetraacetate
• CAS: 439556-55-5
• 化学式: C₃₀H₃₂Co₂N₄O₈
• 分子量: 694.592
• InChiKey: ORNNGGVTXPYNJZ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-苯胺基吡啶 、 cobalt(II) diacetate tetrahydrate 以 甲醇 为溶剂， 以79%的产率得到(N-phenyl-2-pyridinamine)2dicobalt(II) tetraacetate
  参考文献：
  名称：

  2-Anilinopyridinate of Cu(I) and adducts of 2-anilinopyridine and metal acetates.

  摘要：

  The adducts of M(OAc)(2).nH(2)O (M = Cu, Co, Ni, Zn) with 2-anilinopyridine, M(OAc)(2)(PhNHpy), have been synthesized and characterized. The X-ray crystal structure of Cu-2(mu-OAc)(4)(PhNHpy)(2) shows the dimer structure of Cu-2(mu-OAc)(4)(H2O)(2) with the PhNHpy ligand in the axial positions of the water molecules. It is antiferromagnetic (2J= =286 cm(-1)). Signals of the triplet state are observed in its EPR spectrum and the zero field splitting parameter (D=0.33 cm(-1)) has been calculated. The electronic spectra and the strong antiferromagnetism of the cobalt (2J = - 324 cm(-1)) and nickel (2J = - 382 cm(-1)) compounds allow to propose also a dimeric structure for them. By excess of ligand, in the anionic form, the Cu(I) compound Cu(PhNpy) was obtained for which a dinuclear structure with a lineal coordination in Cu(I) is proposed. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)01015-4