Zn(2,2'-dipyridyldicarboxylate)(H₂O)₂ | 1388232-99-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Zn(2,2'-dipyridyldicarboxylate)(H₂O)₂
• 英文别名: Zn(bpdc)(H₂O)₂；[Zn(2,2'-bipyridine-6,6'-dicarboxylate)(H2O)2]；[Zn(bpdc)(H2O)2]
• CAS: 1388232-99-2
• 化学式: C₁₂H₁₀N₂O₆Zn
• 分子量: 343.611
• InChiKey: IXIDUKXGDCEAMQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  zinc(II) nitrate hexahydrate 、 2,2'-联吡啶-6,6'-二羧酸 、 水 反应 72.0h， 以63%的产率得到Zn(2,2'-dipyridyldicarboxylate)(H₂O)₂
  参考文献：
  名称：

  Synthesis, characterization, and interaction with DNA of Cu(II) and Zn(II) complexes with 2,2′-bipyridyl-6,6′-dicarboxylic acid

  摘要：

  Two transition metal complexes, [Cu-2(bpdc)(2)H2O]2H2O (1) and Zn(bpdc)(H2O)(2) (2) (H(2)bpdc=2,2-bipyridine-6,6-dicarboxylic acid), were synthesized and characterized by elemental analysis, IR spectroscopy, and single-crystal X-ray diffraction. Complex 1 is dinuclear with two five-coordinate cupric ions and 2 is mononuclear with one six-coordinate zinc. Interactions of 1 and 2 with DNA have been investigated using UV-Vis absorption spectra. The cleavage reaction on DNA has been monitored by agarose gel electrophoresis.

  DOI：

  10.1080/00958972.2013.806655

文献信息

• Luminescent, second-order NLO and magnetic properties of the hydrogen-bond based network derived from 2,2′-bipyridine-6,6′-dicarboxylate
  作者：Xiaochen Shan、A.O. Ibrahim、Youfu Zhou、Huabin Zhang、Jie Ma、Feilong Jiang、Maochun Hong

  DOI：10.1016/j.inoche.2012.05.048

  日期：2012.8

  Complexes [Zn( bpdc)(H2O)(2)] (1) and [Mn(bpdc)(H2O)(3)]center dot 2.5H(2)O (2) were assembled by 2,2'-bipyridine-6,6'-dicarboxylate (H(2)bpdc) with Zn2+ or Mn2+ under hydro/solvo-thermal conditions. Complexes 1 and 2 are extended from mononuclear to 1D, 2D and 3D supramolecular network step by step with the help of intramolecular weak interactions. The luminescent properties of 1 had been investigated in details, which show intense blue emission with relatively good quantum yield. The 2 displays nonlinear optical (NLO) activity comparable with that of KDP, and exhibits weak antiferromagnetic coupling between the Mn (II) ions by the hydrogen bonds. (C) 2012 Elsevier B.V. All rights reserved.