[manganese(II)(3-aminopyridine)4(azide(1-))2] | 791610-30-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [manganese(II)(3-aminopyridine)4(azide(1-))2]
• CAS: 791610-30-5
• 化学式: C₂₀H₂₄MnN₁₄
• 分子量: 515.442
• InChiKey: MAVVJLJPEICBDC-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  3-氨基吡啶 、 sodium azide 、 manganese (II) nitrate tetrahydrate 在 hydrazoic acid 作用下， 以 水 为溶剂， 以55%的产率得到[manganese(II)(3-aminopyridine)4(azide(1-))2]
  参考文献：
  名称：

  New metal(II) complexes containing monodentate and bridging 3-aminopyridine and azido ligands

  摘要：

  Three new metal (II) complexes namely [Mn(3-ampy)(4)(N-3)(2)] (1), [Cd(3-ampy)(H2O)(4)](n)(SO4)n(.)(H2O)(n) (2) and [Cd(3-ampy)(N-3)(2)](n) (3) (3-ampy = 3-aminopyridine), have been synthesized and characterized by spectroscopic and crystallographic methods. The structure of 1 contains distorted octahedral Mn (II) atoms, monodentate 3-ampy and azide ligands. The structure of 2 consists of a packing of [Cd(3-ampy)(H2O)(4)](2+) cations and SO42- anions and lattice water molecules. The Cd (1) center in the cation is coordinated by four O atoms from aqua molecules [Cd-O from 2.261(3) to 2.409(2) Angstrom] and two N atoms; the hetero nitrogen atoms of 3-ampy [Cd-N 2.262(3) Angstrom], whereas Cd(2) atom is surrounded by four aqua molecules and two nitrogen atoms of two amino groups of 3-ampy molecules [Cd-N 2.378(3) Angstrom]. 3-Aminopyridine, therefore, acts as bidentate bridging ligands generating a 1D chain along [0, 1, -1]. Different hydrogen bonds are formed extending the structure to a 3D network. Complex 3 contains dimeric units Cd2N2 through double mu-1,1 azide bridges, N,N-3-ampy ligand and mu-1,3 azides generating a 3D network structure. There are hydrogen bonds of the type N-(HN)-N-... between the NH2 and azido groups consolidating the structure. The thermal properties of the three complexes have been recorded and discussed. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.06.011