[Cd(1,3-dithiole-2-thione-4,5-dithiolato)(2,2'-bipyridine)]2 | 721911-12-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cd(1,3-dithiole-2-thione-4,5-dithiolato)(2,2'-bipyridine)]2
• CAS: 721911-12-2
• 化学式: C₂₆H₁₆Cd₂N₄S₁₀
• 分子量: 929.92
• InChiKey: WIFMQLWISATIOE-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  Cd2(2,2'-bipyridine)2(OAc)4(H2O)2 、 1,3-dithiole-2-thione-4,5-dithiolate 以 甲醇 为溶剂， 生成 [Cd(1,3-dithiole-2-thione-4,5-dithiolato)(2,2'-bipyridine)]2
  参考文献：
  名称：

  Synthesis and characterisation of two dimeric mixed-ligand cadmium(II) complexes with 1,3-dithiole-2-thione-4,5-dithiolate and diimines

  摘要：

  Two dimeric mixed-ligand cadmium(II) complexes, [Cd(dmit)(bipy)](2) (1), [Cd(dmit)(phen)](2) (2), where dmit(2-) = 1,3-dithiole-2-thione-4,5-dithiolate(2 -), bipy = 2,2'-bipyridine, phen = 1,10-phenanthroline, have been synthesized and characterized by infrared spectrum, UV-vis, H-1 NMR and X-ray structure analyses. Complex 1 is monoclinic, P2(1)/c, with a = 11.6128(14), b = 9.3967(12), c = 14.7629(18) Angstrom, beta = 107.582(2)degrees, V = 1535.7(3) Angstrom(3), Z = 4, and D-c = 2.011 g/cm(3). Complex 2 is monoclinic, P2(1)/c, with a = 9.2924(12), b = 12.4663(11), c = 15.0116(15) Angstrom, beta = 105.403(4)degrees, V = 1676.5(3) Angstrom(3), Z = 4, D-c = 1.937 g/cm(3). Both dimers are extended into interesting one-dimensional supramolecular arrays by short (CdS)-S-... contacts and pi-pi stacking interactions among dmit2- groups. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2004.03.039