2,6-di-(4-(N,N-diphenylamino)phenylacetylenyl)-1,3,5,7-tetramethyl-8-phenyl-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene | 1191265-85-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2,6-di-(4-(N,N-diphenylamino)phenylacetylenyl)-1,3,5,7-tetramethyl-8-phenyl-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene
• CAS: 1191265-85-6
• 化学式: C₅₉H₄₅BF₂N₄
• 分子量: 858.841
• InChiKey: NJCPPLDGMODUAV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  5,5-二氟-2,8-二碘-1,3,7,9-四甲基-10-苯基-5H-二吡咯并[1,2-C:2,1-F][1,3,2]二氮杂硼烷-4-鎓-5-硼 、 4-乙炔基三苯胺 在 copper(l) iodide 、 四(三苯基膦)钯 、 三乙胺 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 12.0h， 以68%的产率得到2,6-di-(4-(N,N-diphenylamino)phenylacetylenyl)-1,3,5,7-tetramethyl-8-phenyl-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene
  参考文献：
  名称：

  Long-wavelength boradiazaindacene derivatives with two-photon absorption activity and strong emission: versatile candidates for biological imaging applications

  摘要：

  Novel D-pi-D-type boradiazaindacene dyes exhibit considerable two-photon absorption cross-section and strong red emission. Cell stained with these dyes show bright intracellular fluorescence. These properties qualify them as competitive candidates for fluorescent bioimaging applications (C) 2009 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tet.2009.08.002

文献信息

• Long-wavelength boradiazaindacene derivatives with two-photon absorption activity and strong emission: versatile candidates for biological imaging applications
  作者：Dakui Zhang、Yaochuan Wang、Yi Xiao、Shixiong Qian、Xuhong Qian

  DOI：10.1016/j.tet.2009.08.002

  日期：2009.9

  Novel D-pi-D-type boradiazaindacene dyes exhibit considerable two-photon absorption cross-section and strong red emission. Cell stained with these dyes show bright intracellular fluorescence. These properties qualify them as competitive candidates for fluorescent bioimaging applications (C) 2009 Published by Elsevier Ltd.