N,N-di(propan-2-yl)but-3-en-1-amine | 14031-89-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-di(propan-2-yl)but-3-en-1-amine
• CAS: 14031-89-1
• 化学式: C₁₀H₂₁N
• 分子量: 155.283
• InChiKey: YJSWOYLDKWDIGR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  11
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  bromozinc(1+),prop-1-ene 、 N,N-di(propan-2-yl)but-3-en-1-amine 以 四氢呋喃 为溶剂， 生成 7-(Hept-1-enyl)diisopropylamin
  参考文献：
  名称：

  有机锌添加物，α-乙基添加物，胺类添加物，acétyléniques和alléniques

  摘要：

  已经研究了一种新反应的一般特征和应用领域，即将α-烯属有机锌化合物加成至不饱和（烯属，炔属和烯丙基）胺上。通过许多实例表明，该反应构成了单亚乙基和二亚乙基胺的一般合成方法。

  DOI：

  10.1016/0022-328x(72)80043-3
• 作为产物：
  描述：

  4-溴-1-丁烯 、 二异丙胺 反应 24.0h， 以19%的产率得到N,N-di(propan-2-yl)but-3-en-1-amine
  参考文献：
  名称：

  Angermund, Klaus; Bogdanovic, Borislav; Koppetsch, Gudrun, Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1986, vol. 41, # 4, p. 455 - 466

  摘要：

  DOI：

文献信息

• Barbier-type allylation of iminium ions generated in situ in aqueous medium
  作者：Idália H.S. Estevam、Lothar W. Bieber

  DOI：10.1016/s0040-4039(02)02667-9

  日期：2003.1

  Iminium ions, generated in aqueous solution from secondary amines and formaldehyde, undergo a Barbier-type allylation mediated by tin, aluminum and zinc. The reaction is catalyzed by copper and produces tertiary homoallylamines in up to 85% yield.

  在水溶液中由仲胺和甲醛生成的亚硝酸根离子会经历由锡，铝和锌介导的Barbier型烯丙基化反应。该反应由铜催化，并以高达85％的产率产生叔均烯丙基胺。
• ADHESIVE COMPOSITIONS AND METHOD FOR BONDING TO RUBBER
  申请人：BRIDGESTONE CORPORATION

  公开号：EP1400577A1

  公开（公告）日：2004-03-24

  An adhesive composition of the present invention comprises (A) a conjugated diene polymer having a weight-average molecular weight of 500 to 100,000 and (B) an electron pair-donating basic compound; or comprises (A) a conjugated diene polymer having a weight-average molecular weight of 500 to 100,000, (C) a compound having in its molecule three or more functional groups selected from the group consisting of acryloyloxy group, methacryloyloxy group and groups represented by the following formula I: wherein R1, R2 and m are the same as defined in the specification, and (D) a compound having in its molecule one or two functional groups selected from the group consisting of acryloyloxy group and methacryloyloxy group. At least a part of the surface of an adherend is coated with the adhesive composition to form an adhesive layer. After optionally irradiating the adhesive layer with ultraviolet light or radiation, the vulcanization is preformed while bringing an unvulcanized rubber into press-contact with the adhesive layer, thereby attaining a strong adhesion between the rubber and the adherend. The rubber/adherend composite thus produced is suitably used for the production of rubber-reinforcing materials and rubber articles.

  本发明的粘合剂组合物包括(A)一种共轭二烯聚合物，其重量平均分子量为 500 至 100,000 和(B)一种电子对捐赠碱性化合物；或包括(A)一种共轭二烯聚合物，其重量平均分子量为 500 至 100,000 和(C)一种化合物，其分子中具有三个或三个以上的官能团，这些官能团选自由丙烯酰氧基、甲基丙烯酰氧基和下式 I 所代表的基团组成的组： 其中 R1、R2 和 m 与说明书中定义的相同，以及 (D) 其分子中具有一个或两个选自丙烯酰氧基和甲基丙烯酰氧基的官能团的化合物。将粘合剂组合物涂覆在被粘物表面的至少一部分，以形成粘合剂层。在用紫外线或辐射照射粘合剂层后，进行硫化，同时将未硫化橡胶与粘合剂层压接触，从而在橡胶和粘合剂之间形成牢固的粘合力。由此生产的橡胶/粘合剂复合材料可用于生产橡胶增强材料和橡胶制品。
• MANUFACTURING METHOD FOR TIRE CORD AND ADHESIVE MATERIAL FOR TIRE CORD
  申请人：Bridgestone Corporation

  公开号：EP1657354A1

  公开（公告）日：2006-05-17

  There is provided a novel production method for a tire cord capable of suppressing the use of a diluent accompanying the fuming of harmful substances and energy consumption. The production of a tire cord 7 comprising a twisted cord 6 and an adhesive layer for rubber on the surface of the twisted cord 6 is characterized by comprising a step of spraying an adhesive material onto the twisted cord 6 for coating. A coating apparatus 1 can be used. The coating apparatus 1 comprises a plurality of coaters 2 for spraying an adhesive onto the surface of the twisted cord 6. The coater 2 comprises a coating nozzle and a coating guide. The coating apparatus 1 further comprises an interlacer 3, a low speed pump 4 and an adhesive tank 5 filled with the adhesive.

  本发明提供了一种新颖的轮胎帘线生产方法，该方法能够减少稀释剂的使用以及有害物质的发烟和能源消耗。轮胎帘子线 7 的生产包括加捻帘子线 6 和加捻帘子线 6 表面的橡胶粘合剂层，其特征在于包括在加捻帘子线 6 上喷涂粘合剂材料的步骤。可以使用涂布装置 1。涂覆装置 1 包括多个涂覆器 2，用于将粘合剂喷涂到加捻帘线 6 的表面。涂布器 2 包括一个涂布喷嘴和一个涂布导向器。涂布装置 1 还包括一个夹层器 3、一个低速泵 4 和一个装满粘合剂的粘合剂罐 5。
• Adhesive composition and process for adhesion using the adhesive composition
  申请人：Bridgestone Corporation

  公开号：EP1757667A2

  公开（公告）日：2007-02-28

  The present invention provides an adhesive composition exhibiting a great adhesive strength between an adherend and an adhesive composition and providing remarkably improved workability in attaching a sheet of an unvulcanized rubber composition by forming a hardened surface of an adhesive layer comprising the adhesive composition and a process for adhesion using the adhesive. The adhesive composition comprises a conjugated diene-based polymer (A) having at least one functional group having a photo-curable unsaturated hydrocarbon group at a chain end, a polymerizable compound (B), a photopolymerization initiator (C) and at least one of an active energy ray-shielding agent (D1) and a metal and/or metal compound (D2).

  本发明提供了一种粘合剂组合物，通过形成包含该粘合剂组合物的粘合剂层的硬化表面和使用该粘合剂的粘合工艺，在被粘物和粘合剂组合物之间显示出很高的粘合强度，并在粘合未硫化橡胶组合物薄片时提供显著改善的可操作性。粘合剂组合物包括共轭二烯基聚合物 (A)，其至少一个官能团的链端具有光固化不饱和烃基；可聚合化合物 (B)；光聚合引发剂 (C)；以及活性能量射线屏蔽剂 (D1) 和金属和/或金属化合物 (D2) 中的至少一种。
• ADHESIVE COMPOSITION, ADHESIVE, AND ADHESIVE TAPE
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3943565A1

  公开（公告）日：2022-01-26

  The following is provided as an adhesive composition which adheres strongly and maintains high static shear stably even when exposed to high temperature and high humidity with respect to poor adhesion adherends such as ethylene propylene diene rubber (EPDM), butyl rubber (IIR), chloroprene rubber (CR), styrene butadiene rubber (SBR), thermoplastic polyolefin rubber, and modified asphalt. An adhesive composition containing an acrylic resin (A) containing a terminal carboxyl-containing monomer (a1) unit represented by the following general formula (1), a (meth)acrylic acid monomer (a2) unit and a hydroxyl-containing monomer (a3) unit; an epoxy crosslinking agent (b1), and an isocyanate crosslinking agent (b2). In general formula (1): R1 represents hydrogen or a methyl group, R2 represents a saturated divalent aliphatic group, an unsaturated divalent aliphatic group, a divalent aromatic group, a saturated divalent alicyclic group, or an unsaturated divalent alicyclic hydrocarbon group, and n is a positive number of not less than 1.

  下面提供一种粘合剂组合物，该组合物即使暴露在高温和高湿环境中，对于粘合力较差的粘合剂，如乙丙橡胶（EPDM）、丁基橡胶（IIR）、氯丁橡胶（CR）、丁苯橡胶（SBR）、热塑性聚烯烃橡胶和改性沥青，也能牢固地粘合并稳定地保持较高的静态剪切力。 一种含有丙烯酸树脂（A）的粘合剂组合物，该丙烯酸树脂含有由以下通式（1）表示的含端羧基单体（a1）单元、（甲基）丙烯酸单体（a2）单元和含羟基单体（a3）单元；环氧交联剂（b1）和异氰酸酯交联剂（b2）。在通式（1）中 R1 代表氢或甲基，R2 代表饱和二价脂肪族基团、不饱和二价脂肪族基团、二价芳香族基团、饱和二价脂环族基团或不饱和二价脂环族烃基团，n 是不小于 1 的正数。