[Eu(H2sal)(Hsal)(sal)*H2O]n | 155659-57-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Eu(H2sal)(Hsal)(sal)*H2O]n
• CAS: 155659-57-7；757238-52-1
• 化学式: C₇H₄O₃*C₇H₅O₃*C₇H₆O₃*Eu*H₂O
• 分子量: 581.32
• InChiKey: CJIBXPKAXIVFHJ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -0.85
• 重原子数：
  32.0
• 可旋转键数：
  3.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  212.58
• 氢给体数：
  3.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  [Eu(H2sal)(Hsal)(sal)*H2O]n 在 air 作用下， 以 neat (no solvent) 为溶剂， 生成 europium(III) oxide
  参考文献：
  名称：

  Synthesis and characterization of two one-dimensional lanthanide coordination polymers

  摘要：

  Two lanthanide coordination polymers [Eu(H(2)sal)(Hsal)(sal).H2O](n) (1) and {[Tb(FUR)(3)(H2O)(2)].DMF}(n) (2) (H(2)sa1, salicylic acid; Hsal(-), o-HOC6H4CO2-; HFUR, alpha-furancarboxylic acid; DMF, N,N-dimethylformamide) were synthesized and characterized by elemental analysis, TG, IR, and luminescence spectra. The crystal structures were determined by X-ray single crystal analysis. Both complexes are one-dimensional polymers. Probably the luminescence quenching of complex 1 is assigned to its special one-dimensional ribbon structure. The vibration energy level caused by the one-dimensional ribbon and located between D-5(0) and F-7(j) maybe is the main reason. Complex 2 displays intense green luminescence under the excitation of UV light. The emission bands at 486, 541, 584, and 618 nm are attributed to the characteristic D-5(4) --> F-7(j) (j = 6, 5, 4, 3) transitions of Tb(III) ions, respectively. (C) 2004 Elsevier B.V All rights reserved.

  DOI：

  10.1016/j.jallcom.2004.03.093
• 作为产物：
  描述：

  水 、 sodium salicylate 、 europium(III) chloride hexahydrate 以 水 为溶剂， 以25.86%的产率得到[Eu(H2sal)(Hsal)(sal)*H2O]n
  参考文献：
  名称：

  Synthesis and characterization of two one-dimensional lanthanide coordination polymers

  摘要：

  Two lanthanide coordination polymers [Eu(H(2)sal)(Hsal)(sal).H2O](n) (1) and {[Tb(FUR)(3)(H2O)(2)].DMF}(n) (2) (H(2)sa1, salicylic acid; Hsal(-), o-HOC6H4CO2-; HFUR, alpha-furancarboxylic acid; DMF, N,N-dimethylformamide) were synthesized and characterized by elemental analysis, TG, IR, and luminescence spectra. The crystal structures were determined by X-ray single crystal analysis. Both complexes are one-dimensional polymers. Probably the luminescence quenching of complex 1 is assigned to its special one-dimensional ribbon structure. The vibration energy level caused by the one-dimensional ribbon and located between D-5(0) and F-7(j) maybe is the main reason. Complex 2 displays intense green luminescence under the excitation of UV light. The emission bands at 486, 541, 584, and 618 nm are attributed to the characteristic D-5(4) --> F-7(j) (j = 6, 5, 4, 3) transitions of Tb(III) ions, respectively. (C) 2004 Elsevier B.V All rights reserved.

  DOI：

  10.1016/j.jallcom.2004.03.093