2-tert-Butyl-4-methyl-6-methylthiomethylphenol | 24785-54-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-tert-Butyl-4-methyl-6-methylthiomethylphenol
• 英文别名: 2-t-butyl-4-methyl-6-methylthiomethylphenol；2-Tert-butyl-4-methyl-6-(methylsulfanylmethyl)phenol
• CAS: 24785-54-4
• 化学式: C₁₃H₂₀OS
• 分子量: 224.367
• InChiKey: RBTCXCFYDWZLHZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  45.5
• 氢给体数：
  1
• 氢受体数：
  2

文献信息

• PROCESS FOR OLIGOMERIZATION OF OLEFINS THAT USES A CATALYTIC COMPOSITION THAT COMPRISES AN ORGANOMETALLIC COMPLEX THAT CONTAINS A PHENOXY LIGAND THAT IS FUNCTIONALIZED BY A HETEROATOM
  申请人：Cazaux Jean-Benoit

  公开号：US20110213190A1

  公开（公告）日：2011-09-01

  The invention describes a process for oligomerization of the olefins into compounds or into a mixture of compounds of general formula CpH2p with 4≦p≦80 that implements a catalytic composition that comprises at least one organometallic complex of an element of group IV that is selected from among titanium, zirconium, or hafnium, whereby said organometallic complex contains at least one aryloxy-type (or phenyloxy-type) ligand that is functionalized by a heteroatom that is selected from among nitrogen, oxygen, phosphorus or sulfur or by an aromatic group.

  该发明描述了一种将烯烃寡聚成通式CpH2p（其中4≦p≦80）的化合物或化合物混合物的过程，该过程实施了一种催化组合物，该催化组合物至少包括一种来自IV族元素中的钛、锆或铪的有机金属配合物，所述有机金属配合物至少包含一种被氮、氧、磷或硫或芳香族基团选中的芳氧基（或苯氧基）配体。
• Improved method for the preparation of 3-Amino-2-chloro-4-alkylpyridines
  申请人：BOEHRINGER INGELHEIM PHARMACEUTICALS INC.

  公开号：EP0598396A1

  公开（公告）日：1994-05-25

  A process for the preparation of a 3-amino-2-chloro-4-alkylpyridine of the formula:    wherein R1 is a linear, branched or cyclic hydrocarbon of from one to eight carbon atoms, optionally substituted with one or more electron stabilizing groups, an intermediate in the preparation of certain 5,11-dihydro-6H-dipyrido[3,2-b:2',3'-e][1,4]diazepine compounds useful in the prevention and treatment of HIV infection.

  一种制备式为 3-氨基-2-氯-4-烷基吡啶的工艺： 其中 R1 为 1 至 8 个碳原子的线性、支链或环状烃，任选被一个或多个电子稳定基团取代、 是制备某些 5,11-二氢-6H-二吡啶并[3,2-b:2',3'-e][1,4]二氮杂卓化合物的中间体，可用于预防和治疗 HIV 感染。
• US5654429A
  申请人：——

  公开号：US5654429A

  公开（公告）日：1997-08-05
• US9260358B2
  申请人：——

  公开号：US9260358B2

  公开（公告）日：2016-02-16
• [EN] METHOD FOR OLIGOMERISING OLEFINS USING A CATALYTIC COMPOSITION COMPRISING AN ORGANOMETAL COMPLEX CONTAINING A PHENOXY LIGAND FUNCTIONALISED BY A HETEROATOM<br/>[FR] PROCÉDÉ D'OLIGOMÉRISATION DES OLÉFINES UTILISANT UNE COMPOSITION CATALYTIQUE COMPRENANT UN COMPLEXE ORGANOMÉTALLIQUE CONTENANT UN LIGAND PHENOXY FONCTIONNALISÉ PAR UN HÉTÉRO-ATOME
  申请人：INST FRANCAIS DU PETROLE

  公开号：WO2008142295A1

  公开（公告）日：2008-11-27

  [EN] The invention relates to a method for oligomerising olefins into compounds or a mixture of compounds of the general formula CpH2p with 4 = p = 80, that uses a catalytic composition containing at least one organometal compound of an element of the Group IV selected from titanium, zirconium and hafnium, said organometal compound containing at least one ligand of the aryloxy (or phenoxy type) functionalised by a heteroatom selected from nitrogen, oxygen, phosphorus or sulphur or by an aromatic group.
  [FR] L'invention décrit un procédé d'oligomérisation des oléfines en composés ou en un mélange de composés de formule générale CpH2p avec 4 = p = 80 mettant en oeuvre un composition catalytique comprenant au moins un complexe organométallique d'un élément du groupe IV choisi parmi le titane, le zirconium ou l'hafnium, ledit complexe organométallique contenant au moins un ligand de type aryloxy (ou phenoxy) fonctionnalisé par un hétéro-atome choisi parmi l'azote, l'oxygène, le phosphore ou le soufre ou par un groupement aromatique.