1,3,2-Benzodioxaborole, 2,2'-(9,9-dihexyl-9H-fluorene-2,7-diyl)bis- | 856570-41-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 1,3,2-Benzodioxaborole, 2,2'-(9,9-dihexyl-9H-fluorene-2,7-diyl)bis-
• 英文别名: 2-[7-(1,3,2-benzodioxaborol-2-yl)-9,9-dihexylfluoren-2-yl]-1,3,2-benzodioxaborole
• CAS: 856570-41-7
• 化学式: C₃₇H₄₀B₂O₄
• 分子量: 570.344
• InChiKey: VGHDCYXNEIAYAT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.23
• 重原子数：
  43
• 可旋转键数：
  12
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  邻苯二酚 、 9,9-二己基芴-2,7-二硼酸 以 甲苯 为溶剂， 反应 18.0h， 以0.4789 g的产率得到1,3,2-Benzodioxaborole, 2,2'-(9,9-dihexyl-9H-fluorene-2,7-diyl)bis-
  参考文献：
  名称：

  Self-Assembling Poly(dioxaborole)s as Blue-Emissive Materials

  摘要：

  Conjugated, borole-linked polymers have been self-assembled based on boronate ester formation between a fluorene-2,7-diboronic acid and 1,2,4,5-tetrahydroxybenzene. Readily soluble polymers with molecular weights approaching 60 000 have been generated with materials exhibiting extended conjugation over approximately 3-5 borole linkages. Emission from these polymers reaches into the visible (blue) range, representing a novel class of blue-emitting materials.

  DOI：

  10.1021/ja065986c

文献信息

• Self-Assembling Poly(dioxaborole)s as Blue-Emissive Materials
  作者：Weijun Niu、Mark D. Smith、John J. Lavigne

  DOI：10.1021/ja065986c

  日期：2006.12.1

  Conjugated, borole-linked polymers have been self-assembled based on boronate ester formation between a fluorene-2,7-diboronic acid and 1,2,4,5-tetrahydroxybenzene. Readily soluble polymers with molecular weights approaching 60 000 have been generated with materials exhibiting extended conjugation over approximately 3-5 borole linkages. Emission from these polymers reaches into the visible (blue) range, representing a novel class of blue-emitting materials.