| 1401063-73-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1401063-73-7
• 化学式: C₂₆H₂₆N₄O₈Pd₂
• 分子量: 735.354
• InChiKey: JWDRKIZPJVMPKR-JRBLGOLTSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(2-pyridylcarbonylaldehyde)-o-phenylenediamine 、 palladium diacetate 以 乙腈 为溶剂， 反应 6.0h， 以86%的产率得到
  参考文献：
  名称：

  Palladium(II) complex with a potential N4-type Schiff-base ligand as highly efficient catalyst for Suzuki–Miyaura reactions in aqueous media

  摘要：

  Two new air-stable palladium(II) complexes containing a N-4-Schiff-base ligand have been synthesized and investigated as catalysts for the Suzuki-Miyaura reactions. The binuclear complex 2 has proven to be an excellent catalyst for additive-free Suzuki-Miyaura reactions of aryl bromides in neat water at room temperature and aryl chlorides in aqueous-glycerol at 80 degrees C. Satisfactory to excellent yields of biaryls are obtained with a wide range of substrates with relatively low loading of catalyst. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.08.026
• 作为试剂：
  描述：

  4-甲苯硼酸 、 1-溴-4-硝基苯 在 C₂₆H₂₆N₄O₈Pd₂ 、 potassium carbonate 作用下， 以 水 为溶剂， 反应 16.0h， 以94%的产率得到4-甲基-4'-硝基联苯
  参考文献：
  名称：

  Palladium(II) complex with a potential N4-type Schiff-base ligand as highly efficient catalyst for Suzuki–Miyaura reactions in aqueous media

  摘要：

  Two new air-stable palladium(II) complexes containing a N-4-Schiff-base ligand have been synthesized and investigated as catalysts for the Suzuki-Miyaura reactions. The binuclear complex 2 has proven to be an excellent catalyst for additive-free Suzuki-Miyaura reactions of aryl bromides in neat water at room temperature and aryl chlorides in aqueous-glycerol at 80 degrees C. Satisfactory to excellent yields of biaryls are obtained with a wide range of substrates with relatively low loading of catalyst. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.08.026