endosulfdanesulfate | 83601-84-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫代羰基化合物
• 英文名称: endosulfdanesulfate
• 英文别名: endosulfan-sulphate；endosulfan II；endosulfan sulfate；(1R,2R,8S,9S)-1,9,10,11,12,12-hexachloro-4,6-dioxa-5lambda6-thiatricyclo[7.2.1.02,8]dodec-10-ene 5,5-dioxide；(1R,2R,8S,9S)-1,9,10,11,12,12-hexachloro-4,6-dioxa-5λ6-thiatricyclo[7.2.1.02,8]dodec-10-ene 5,5-dioxide
• CAS: 83601-84-7
• 化学式: C₉H₆Cl₆O₄S
• 分子量: 422.928
• InChiKey: AAPVQEMYVNZIOO-ZBKCKJIOSA-N

物化性质

• 沸点：
  480.7±45.0 °C(Predicted)
• 密度：
  1.94±0.1 g/cm3(Predicted)
• 碰撞截面：
  172.11 Ų [M-H]-; 174.7 Ų [M+Cl]-

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  20
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  61
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  alpha-endosulfan 以 甲醇 为溶剂， 反应 24.0h， 以9 mg的产率得到(1R,2R,6S,7S)-1,7,8,9,10,10-Hexachloro-4-oxa-tricyclo[5.2.1.0^2,6]dec-8-ene
  参考文献：
  名称：

  Dureja, P.; Mukerjee, S. K., Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1982, vol. 21, # 5, p. 411 - 413

  摘要：

  DOI：

文献信息

• [EN] NUCLEOPHILIC ENHANCEMENT OF BETA-ENDOSULFAN IN AN ENDOSULFAN MIX<br/>[FR] AMELIORATION NUCLEOPHILE DE BETA-ENDOSULFAN DANS UN MELANGE D'ENDOSULFANS
  申请人：CROP CARE AUSTRALASIA PTY LTD

  公开号：WO2004103989A1

  公开（公告）日：2004-12-02

  The invention relates to a process for the preparation of endosulfan enriched in the ß-isomer thereof (ß-endosulfan). The invention also provides a process for enriching the ß-isomer content of a mixture of a- and ß-endosulfan, and to processes for obtaining ß-endosulfan in substantially pure form.

  本发明涉及一种制备富含ß-内吸砒的过程（ß-内吸砒）。本发明还提供了一种富集a-和ß-内吸砒混合物中ß-异构体含量的过程，以及获取ß-内吸砒的过程，其形式基本纯净。
• Detection of haptens in immunoassay techniques
  申请人：Research Corporation

  公开号：EP0242589A2

  公开（公告）日：1987-10-28

  The present invention relates to a method of producing monoclonal antibodies capable of being utilized in hapten sandwich assays, and the antibodies produced by this method. It also relates to a method of detecting haptens by utilizing these antibodies in a sandwich assay. Also provided is a method of hapten detection in a nonaqueous sample.

  本发明涉及一种生产可用于杂合体夹心检测的单克隆抗体的方法，以及用该方法生产的抗体。 本发明还涉及一种在夹心检测中利用这些抗体检测杂合体的方法。 本发明还提供了一种在非水样品中检测杂合体的方法。
• Improved solid phase microextraction of trace amounts of organic analytes
  申请人：MALLINCKRODT BAKER, Inc.

  公开号：EP0730143A2

  公开（公告）日：1996-09-04

  A method for enhancing detection sensitivity of suspected trace amounts of organic analytes and particularly semivolatile organic analytes extractable from a sample by an organic solvent carrier matrix and subsequent extraction and analysis of said trace organic analytes by SPME wherein the improvement comprises exchanging the organic solvent carrier matrix containing the trace organic analytes for an aqueous carrier matrix before performing SPME fiber extraction and detection of the trace organic analytes. The diagram, a chromatogram obtained with an ECD detector, illustrates the determination of chlorinated pesticides at the sub-parts per trillion level.

  一种用于提高可通过有机溶剂载体基质从样品中萃取的疑似痕量有机分析物，特别是半挥发性有机分析物的检测灵敏度的方法，以及随后通过 SPME 对所述痕量有机分析物进行萃取和分析的方法，其中的改进包括在进行 SPME 纤维萃取和检测痕量有机分析物之前，将含有痕量有机分析物的有机溶剂载体基质交换为水性载体基质。该图是使用 ECD 检测器获得的色谱图，说明了亚万亿pps 级氯化农药的测定结果。
• Functional mung bean-derived compositions
  申请人：Hampton Creek, Inc.

  公开号：US10321705B2

  公开（公告）日：2019-06-18

  Provided herein are methods for producing a mung bean protein isolate having high functionality for a broad range of food applications. In some embodiments, the methods for producing the isolate comprise one or more steps selected from: (a) extracting one or more mung bean proteins from a mung bean protein source in an aqueous solution, for example, at a pH between about 6.5-10.0; (b) purifying protein from the extract using at least one of two methods: (i) precipitating protein from the extract at a pH near the isoelectric point of a globulin-rich fraction, for example a pH between about 5.0-6.0; and/or (ii) fractionating and concentrating protein from the extract using filtration such as microfiltration, ultrafiltration or ion-exchange chromatography; and (c) recovering purified protein isolate.

  本文提供了生产具有高功能性的绿豆蛋白分离物的方法，可用于广泛的食品应用。在一些实施方案中，生产分离物的方法包括一个或多个步骤，这些步骤选自：(a) 从绿豆蛋白源的水溶液中提取一种或多种绿豆蛋白，例如在 pH 值约为 6.5-10.0之间；(b) 使用以下两种方法中的至少一种从提取物中纯化蛋白质：(i) 在接近富含球蛋白馏分等电点的pH值下，例如在约5.0-6.0之间的pH值下，从提取物中沉淀蛋白质；和/或(ii) 使用过滤法，例如微滤、超滤或离子交换色谱法，从提取物中分馏和浓缩蛋白质；以及(c) 回收纯化的蛋白质分离物。
• Functionalized support for analytical sample preparation
  申请人：Agilent Technologies, Inc.

  公开号：US10436684B2

  公开（公告）日：2019-10-08

  Aspects of the present disclosure include a solid phase sorbent for preparation of analytical samples. The solid phase sorbent includes particles that are surface modified with an α-cyclodextrin moiety. Also provided is a method of reducing matrix effects in an analytical sample. In some embodiments, the method includes contacting a sample comprising a matrix-interfering agent and an analyte with α-cyclodextrin modified particles to produce a contacted sample wherein the matrix-interfering agent binds to the α-cyclodextrin modified particles; separating the α-cyclodextrin modified particles from the contacted sample to produce a matrix-reduced composition; and detecting the analyte in the matrix-reduced composition. Systems for practicing the subject methods are provided that include the subject solid phase sorbent.

  本公开的各个方面包括一种用于制备分析样品的固相吸附剂。固相吸附剂包括用 α-环糊精分子进行表面修饰的颗粒。还提供了一种减少分析样品中基质效应的方法。在一些实施方案中，该方法包括将包含基质干扰剂和分析物的样品与α-环糊精修饰颗粒接触，以产生接触样品，其中基质干扰剂与α-环糊精修饰颗粒结合；从接触样品中分离α-环糊精修饰颗粒，以产生基质还原组合物；以及检测基质还原组合物中的分析物。所提供的用于实施所述方法的系统包括所述固相吸附剂。