copper(II)(para-(tert-butyl)benzoic acid N',N'-dimethylhydrazine(-H))2 | 1402164-67-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: copper(II)(para-(tert-butyl)benzoic acid N',N'-dimethylhydrazine(-H))2
• 英文别名: [Cu(para-tert-butylbenzoic acid N',N'-dimethylhydrazide(-1H))2]
• CAS: 1402164-67-3
• 化学式: C₂₆H₃₈CuN₄O₂
• 分子量: 502.159
• InChiKey: MHCQTDJTRNIVET-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 2',2'-dimethyl-para-tert-butylbenzohydrazide 在 aq. NH₃ 作用下， 以 乙醇 、 水 为溶剂， 以85%的产率得到copper(II)(para-(tert-butyl)benzoic acid N',N'-dimethylhydrazine(-H))2
  参考文献：
  名称：

  Crystal structure of copper(II) chelate with para-(tert-butyl)benzoic acid N′,N′-dimethylhydrazide

  摘要：

  X-Ray diffraction analysis was performed for the copper(II) chelate with para-(tert-butyl)benzoic acid N',N'-dimethylhydrazide, Cu(p-(tert-Bu)C6H4CONHNMe2)(2) (I). The reagent functions as a bidentate (O,N(2)) ligand giving a five-membered copper-containing ring. The molecule is centrosymmetric. The Cu atom and the metal rings lie in the same plane. The coordination polyhedron of copper is a slightly distorted square. The crystals are monoclinic: a = 16.2634(14) , b = 9.0415(8) , c = 9.6415(9) , alpha = 90A degrees, beta = 100.052(7)A degrees, Z = 2, space group P2(1)/c.

  DOI：

  10.1134/s1070328412070044

文献信息

• Extraction and complexation of copper(II) with para-tert-butylbenzhydrazide and its N′,N′-dimethyl derivative
  作者：V. Yu. Gusev、D. A. Muksinova、A. V. Radushev

  DOI：10.1134/s1070363212040135

  日期：2012.4

  The extraction of copper(II) with the para-tert-butylbenzoic acid hydrazide and related N',N'-dimethyl derivative was studied. The composition and structure of the extracted complexes were determined, the mechanism of extraction of copper(II) in different media was suggested, the extraction constant was calculated. The copper(II) complex compounds with these reagents were isolated.