2-(1',1'-dibutylamyl)-4,6-dimethyl-5-phenyl-1,3,2,5-dioxaboraphosphorinane | 135309-27-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(1',1'-dibutylamyl)-4,6-dimethyl-5-phenyl-1,3,2,5-dioxaboraphosphorinane
• CAS: 135309-27-2
• 化学式: C₂₃H₄₀BO₂P
• 分子量: 390.354
• InChiKey: IJTOTWUMAVGHJA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.33
• 重原子数：
  27.0
• 可旋转键数：
  11.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.74
• 拓扑面积：
  18.46
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  copper(l) iodide 、 2-(1',1'-dibutylamyl)-4,6-dimethyl-5-phenyl-1,3,2,5-dioxaboraphosphorinane 以 吡啶 为溶剂， 以60%的产率得到{(2-(1',1'-dibutylamyl)-4,6-dimethyl-5-phenyl-1,3,2,5-dioxaboraphosphorinane)pyridine cuprous iodide}
  参考文献：
  名称：

  Synthesis and several properties of 1, 3, 2, 5-dioxaboraphosphorinanes with a branched substituent at the boron atom

  摘要：

  Bis (alpha-hydroxyalkyl)phenylphosphines react with alpha-iminoboranes in protic solvents such as dihydric alcohols to give 2-(1',1'-dibutylamyl)-4,6-di-R-5-phenyl-1,3,2,5-dioxaboraphosphorinanes, which react with CuI in pyridine to form [LCuI(Py)] complexes. PMR spectroscopy showed that the phosphorus-containing ligands exist as a single stereoisomer.

  DOI：

  10.1007/bf00958010
• 作为产物：
  描述：

  三丁基硼 、 异氰酸叔丁酯 、 bis(α-hydroxyethyl)phenylphosphine 以 乙醇 为溶剂， 以30%的产率得到2-(1',1'-dibutylamyl)-4,6-dimethyl-5-phenyl-1,3,2,5-dioxaboraphosphorinane
  参考文献：
  名称：

  Synthesis and several properties of 1, 3, 2, 5-dioxaboraphosphorinanes with a branched substituent at the boron atom

  摘要：

  Bis (alpha-hydroxyalkyl)phenylphosphines react with alpha-iminoboranes in protic solvents such as dihydric alcohols to give 2-(1',1'-dibutylamyl)-4,6-di-R-5-phenyl-1,3,2,5-dioxaboraphosphorinanes, which react with CuI in pyridine to form [LCuI(Py)] complexes. PMR spectroscopy showed that the phosphorus-containing ligands exist as a single stereoisomer.

  DOI：

  10.1007/bf00958010