| 182420-38-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 182420-38-8
• 化学式: C₈₀H₉₆F₁₆FeN₈O₁₂Si₄
• 分子量: 1833.85
• InChiKey: MMSSETKWGDPFFS-BIXJGOBDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 氢氟酸 在 水 作用下， 以 二氯甲烷 、 水 为溶剂， 生成
  参考文献：
  名称：

  Metalloporphyrinosilicas: a new class of hybrid organic–inorganic materials acting as selective biomimetic oxidation catalysts

  摘要：

  New hybrid organic-inorganic materials are prepared by hydrolysis and polycondensation, or cocondensation with tetraethoxysilane, of iron porphyrins bearing a trifluorosilyl function; despite their insolubility, these 'metalloporphyrinosilicas' are efficient catalysts for alkene epoxidation by PhIO or Bu(t)OOH and alkane hydroxylation by PhIO, the iron porphyrinosilicas with low specific surface areas (approximate to 60 m(2) g(-1)) catalysing a shape-selective hydroxylation of alkane mixtures.

  DOI：

  10.1039/cc9960002037
• 作为产物：
  描述：

  3-氨基丙基三乙氧基硅烷 、 5,10,15,20-tetra(pentafluorophenyl)porphyrin Fe(III) 在 三乙胺 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  Metalloporphyrinosilicas: a new class of hybrid organic–inorganic materials acting as selective biomimetic oxidation catalysts

  摘要：

  New hybrid organic-inorganic materials are prepared by hydrolysis and polycondensation, or cocondensation with tetraethoxysilane, of iron porphyrins bearing a trifluorosilyl function; despite their insolubility, these 'metalloporphyrinosilicas' are efficient catalysts for alkene epoxidation by PhIO or Bu(t)OOH and alkane hydroxylation by PhIO, the iron porphyrinosilicas with low specific surface areas (approximate to 60 m(2) g(-1)) catalysing a shape-selective hydroxylation of alkane mixtures.

  DOI：

  10.1039/cc9960002037