[Pd(2,2'-bipyridine)(N-(2-hydroxyphenyl)-p-toluenesulfonamide(-2H))] | 1079321-06-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Pd(2,2'-bipyridine)(N-(2-hydroxyphenyl)-p-toluenesulfonamide(-2H))]
• 英文别名: [Pd(bpy)(sulf)]
• CAS: 1079321-06-4
• 化学式: C₂₃H₁₉N₃O₃PdS
• 分子量: 523.908
• InChiKey: UISRZCFYUJLPBH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (2,2-联吡啶)二氯钯(II) 、 N-(2-羟基-苯基)-4-甲基-苯磺酰胺 以 not given 为溶剂， 生成 [Pd(2,2'-bipyridine)(N-(2-hydroxyphenyl)-p-toluenesulfonamide(-2H))]
  参考文献：
  名称：

  The first structurally characterised cyclotriphosphazene substituted with a sulfonamide nitrogen

  摘要：

  The reaction between two equivalents of N-(2-hydroxyphenyl)-p-toluenesulfonamide (H(2)sulf) and [N3P3(biph)(2)Cl-2] (H(2)biph = 2,2'-biphenol) produces the compound bis(2,2'-biphenylato)bis(2-oxyphenyl)-p-toluenesulfonamide cyclotriphosphazene (H2L) containing two geminal Hsulf moieties. Further reaction of H2L in basic conditions results in the removal of the sulfonamide arm and the slow formation of a novel phosphazene containing the spirocyclic sulf moiety. When this occurs in the presence of [Pd(bpy)Cl-2] the reaction is facile and the new complex [Pd(bpy)(sulf)] (2) is also formed. Compounds H2L, 1 and 2 have all been characterised by single crystal X-ray crystallography. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.05.014