[(((CH3)2CHNH)C(NCH(CH3)2)2)2Zr(benzyl)(η2-N(C6H3(CH3)2)CCH2C6H5)] | 397251-13-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯烷类
• 英文名称: [(((CH3)2CHNH)C(NCH(CH3)2)2)2Zr(benzyl)(η2-N(C6H3(CH3)2)CCH2C6H5)]
• CAS: 397251-13-7
• 化学式: C₄₃H₆₇N₇Zr
• 分子量: 773.276
• InChiKey: VFRMWESRTZBHHD-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  [(((CH3)2CHNH)C(NCH(CH3)2)2)2Zr(benzyl)(η2-N(C6H3(CH3)2)CCH2C6H5)] 以 not given 为溶剂， 生成 [(((CH3)2CHNH)C(NCH(CH3)2)2)2Zr(N(C6H3(CH3)2))]
  参考文献：
  名称：

  Transformations of Aryl Isocyanide on Guanidinate-Supported Organozirconium Complexes To Yield Terminal Imido, Iminoacyl, and Enediamido Ligands

  摘要：

  Reactions of aryl isocyanide with bis(guanidinate) Zr(IV) hydrocarbyl complexes are presented. With 1 equiv of Ar'NC the ultimate products are the terminal Zr imido complexes [{(R'NR")C(NR)(2)}(2)ZrN(2,6-Me2C6H3)] (3, R = R' = (PR)-P-i, R" = H; 5, R = Pr-i, R' = R" = Me), which are derived via a unique transformation from intermediate eta(2)-iminoacyl species. With 2 equiv of Ar'NC, [{(Me2N)C((NPr)-Pr-i)(2)}(2)Zr(eta(2)-Ar'N=CMe)(2)] (6) was isolated. Mild thermolysis of 6 generates an enediamido complex via intramolecular coupling of the iminoacyl groups.

  DOI：

  10.1021/om0108548
• 作为产物：
  描述：

  [(((CH3)2CHNH)C(NCH(CH3)2)2)2Zr(benzyl)2] 、 2,6-二甲基苯基异腈 以 not given 为溶剂， 生成 [(((CH3)2CHNH)C(NCH(CH3)2)2)2Zr(benzyl)(η2-N(C6H3(CH3)2)CCH2C6H5)]
  参考文献：
  名称：

  Transformations of Aryl Isocyanide on Guanidinate-Supported Organozirconium Complexes To Yield Terminal Imido, Iminoacyl, and Enediamido Ligands

  摘要：

  Reactions of aryl isocyanide with bis(guanidinate) Zr(IV) hydrocarbyl complexes are presented. With 1 equiv of Ar'NC the ultimate products are the terminal Zr imido complexes [{(R'NR")C(NR)(2)}(2)ZrN(2,6-Me2C6H3)] (3, R = R' = (PR)-P-i, R" = H; 5, R = Pr-i, R' = R" = Me), which are derived via a unique transformation from intermediate eta(2)-iminoacyl species. With 2 equiv of Ar'NC, [{(Me2N)C((NPr)-Pr-i)(2)}(2)Zr(eta(2)-Ar'N=CMe)(2)] (6) was isolated. Mild thermolysis of 6 generates an enediamido complex via intramolecular coupling of the iminoacyl groups.

  DOI：

  10.1021/om0108548