2-tert.-Butyl-6-(1,1-dimethyl-propyl)-phenol | 92860-12-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-tert.-Butyl-6-(1,1-dimethyl-propyl)-phenol
• 英文别名: 2-t-Butyl-6-t-amylphenol；2-tert-butyl-6-(2-methylbutan-2-yl)phenol
• CAS: 92860-12-3
• 化学式: C₁₅H₂₄O
• 分子量: 220.355
• InChiKey: CSYPHHNLCRGEHA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• COMPOSITIONS COMPRISING POLYPHOSPHONATES AND ADDITIVES THAT EXHIBIT AN ADVANTAGEOUS COMBINATION OF PROPERTIES, AND METHODS RELATED THERETO
  申请人：Freitag Dieter

  公开号：US20070203269A1

  公开（公告）日：2007-08-30

  Disclosed are new compositions consisting of polyphosphonates and specific additive compositions that exhibit superior resistance to degradation due to exposure to air, high temperature and air, moisture or combinations thereof. Also disclosed are polymer mixtures or blends comprising these polyphosphonates/additive compositions and commodity and engineering plastics and articles produced therefrom. Further disclosed are articles of manufacture produced from these materials, such as fibers, films, coated substrates, moldings, foams, fiber-reinforced articles, or any combination thereof.

  公开了由聚磷酸酯和特定添加剂组成的新组合物，其表现出对暴露于空气、高温和空气、湿气或其组合物的降解具有优越的抵抗力。还公开了聚磷酸酯/添加剂组合物与商品和工程塑料的聚合物混合物或混合物，以及由此制成的制品。还公开了由这些材料制成的制品，例如纤维、薄膜、涂层基材、成型品、泡沫、纤维增强制品或其任何组合。
• Method of producing p-Hydroxyphenylalkanols
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20030195379A1

  公开（公告）日：2003-10-16

  Disclosed are a method of producing p-hydroxyphenylalkanol of formula.(I): 1 wherein R 1 and R 2 independently represent hydrogen, an alkyl or a phenyl which may be substituted with an alkyl, or the like, R 3 , R 4 , R 5 , R 6 and R 7 independently represent hydrogen, an alkyl or the like and n denotes an integer from 0 to 7, the method being characterized in that a phenol compound of formula (II): 2 wherein R 1 and R 2 respectively represent the aforementioned meaning, is reactedwith an unsaturated alcohol of formula (III): R 3 R 4 C=C(R 5 )-C(R 6 )(R 7 )-(CH 2 ) n -OH (III) wherein R 3 , R 4 , R 5 , R 6 , R 7 and n respectively represent the same as defined above, in the presence of (A) at least one compound selected from the group consisting of alkali metals, alkali metal compounds, alkaline earth metals and alkaline earth metal compounds and (B) at least one compound selected from the group consisting of transition metals and transition metal compounds, and the like.

  公开了一种制备式（I）的对羟基苯基醇的方法，其中R1和R2分别独立表示氢、烷基或苯基，可以用烷基或类似物取代，R3、R4、R5、R6和R7分别独立表示氢、烷基或类似物，n表示0至7的整数。该方法的特征在于，在（A）碱金属、碱金属化合物、碱土金属和碱土金属化合物组成的群体中选择至少一种化合物，以及在（B）过渡金属和过渡金属化合物组成的群体中选择至少一种化合物的存在下，将式（II）的酚化合物与式（III）的不饱和醇反应：R3R4C=C(R5)-C(R6)(R7)-(CH2)n-OH（III），其中R3、R4、R5、R6、R7和n分别表示上述定义的相同物。
• Alkylation of 2,6-di-tert.-alkylphenols with alkanediols
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0028200A1

  公开（公告）日：1981-05-06

  There is a process disclosed for alkylating the nucleus of a phenol, said process comprising reacting an α,ω alkanediol containing from 3 to 8 carbon atoms with a phenol having an unsubstituted nuclear position para to the phenolic hydroxyl group; said phenol being selected from the group of alkylated phenols having tertiary alkyl groups of 4 to 8 carbon atoms in both positions ortho to the phenolic hydroxyl group, in the presence of an alkali metal hydroxide or alkoxide or alkali metal at a temperature from 200 to 300° C while continuously removing the water by-product as it forms and obtaining as a product said phenol having a primary hydroxy terminated alkyl group of 3 to 8 carbon atoms in said para position.

  公开了一种使苯酚核烷基化的工艺，该工艺包括在碱金属氢氧化物或碱金属氧化物或碱金属存在下，在 200 至 300 摄氏度的温度下，使含有 3 至 8 个碳原子的 α、ω 烷二醇与具有与酚羟基对位的未取代核位置的苯酚反应；所述苯酚选自在与酚羟基正交的两个位置上具有 4 至 8 个碳原子的叔烷基的烷基化苯酚组，同时不断除去形成的水副产物，并得到在所述对位位置上具有 3 至 8 个碳原子的伯羟基末端烷基的所述苯酚作为产物。
• Method of producing p-hydroxyphenylalkanols
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1348686A1

  公开（公告）日：2003-10-01

  Disclosed is a method of producing a p-hydroxyphenylalkanol of formula (I): wherein R1 and R2 independently represent hydrogen, alkyl, phenyl which may be substituted with alkyl, or the like, R3, R4, R5, R6 and R7 independently represent hydrogen or alkyl and n denotes an integer from 0 to 7, which method comprises reacting a phenol compound of formula (II): wherein R1 and R2 are as defined above, with an unsaturated alcohol of formula (III):         R3R4C=C(R5)-C(R6)(R7)-(CH2)n-OH     (III) wherein R3, R4, R5, R6, R7 and n are as defined above,    in the presence of (A) at least one member selected from the group consisting of alkali metals, alkali-metal compounds, alkaline earth metals and alkaline earth metal compounds and (B) at least one member selected from the group consisting of transition metals and transition metal compounds, or    in the presence of (a) an alkali metal or an alkali metal compound, and (b) an alkaline earth metal or an alkaline earth metal compound.

  本发明公开了一种生产式(I)的对羟基苯烷醇的方法： 其中 R1 和 R2 独立地代表氢、烷基、可被烷基取代的苯基或类似物，R3、R4、R5、R6 和 R7 独立地代表氢或烷基，n 表示 0 至 7 的整数，该方法包括使式（II）的苯酚化合物与式（III）的不饱和醇反应： 其中 R1 和 R2 如上定义，与式 (III) 的不饱和醇反应： R3R4C=C(R5)-C(R6)(R7)-(CH2)n-OH (III) 其中 R3、R4、R5、R6、R7 和 n 如上定义、 (A)至少一种选自碱金属、碱金属化合物、碱土金属和碱土金属化合物组成的组，和 (B)至少一种选自过渡金属和过渡金属化合物组成的组，或 (a) 碱金属或碱金属化合物，和 (b) 碱土金属或碱土金属化合物。
• 1,2-ALKANE POLYOL-CONTAINING COMPOSITION
  申请人：Osaka Organic Chemical Ind., Ltd.

  公开号：EP2985017A1

  公开（公告）日：2016-02-17

  Provided is a composition containing, as an alkane polyol, a C4-18 1,2-alkane polyol in which the degradation over time of the C4-18 1,2-alkane polyol, which has inferior chemical stability and degrades easily, is suppressed, the composition being suitable for use in a cosmetic, an inkjet ink, a fiber or a coating material such as a paint. A composition containing 1,2-alkane polyol that can be used in a cosmetic, an inkjet ink, a raw material for fibers or a coating material, the alkane polyol being a C4-18 1,2-alkane polyol, and the composition containing a radical scavenger.

  本发明提供了一种含有 C4-18 1,2-烷烃多元醇作为烷烃多元醇的组合物，在该组合物中，化学稳定性较差且容易降解的 C4-18 1,2-烷烃多元醇随时间推移的降解受到抑制，该组合物适用于化妆品、喷墨墨水、纤维或涂料等涂层材料。一种含有 1,2-烷烃多元醇的组合物，可用于化妆品、喷墨墨水、纤维原料或涂层材料，烷烃多元醇为 C4-18 1,2-烷烃多元醇，组合物中含有自由基清除剂。