tetra(2-hydroxyethyleneoxy)phthalocyaninatozinc(II) | 505029-66-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: tetra(2-hydroxyethyleneoxy)phthalocyaninatozinc(II)
• CAS: 505029-66-3
• 化学式: C₄₀H₃₂N₈O₈Zn
• 分子量: 818.133
• InChiKey: DIUYJRQCFSJORY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  、 zinc diacetate 以 喹啉 为溶剂， 以34%的产率得到tetra(2-hydroxyethyleneoxy)phthalocyaninatozinc(II)
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF PHTHALOCYANINES WITH NON-IONIC SOLUBILIZING GROUPS

  摘要：

  Two new mono substituted phthalonitrile derivatives (1) and (2) have been prepared by a nucleophilic displacement reaction of 4-nitrophthalonitrile with ethylene glycol or tetraethylene glycol. Novel metal-free and metallated phthalocyanines (pcs) have been synthesized by cyclotetramerization of these phthalonitriles in the presence of hydroquinone or anhydrous divalent metal salt to form Ni(11), Co(11), Cu(11) and Zn(11) adducts. The newly synthesized pcs are very soluble in polar solvents such as H2O to THF. The complexes have been characterized by elemental analyses, IR, H-1 and C-13 NMR, and UV-Vis spectra.

  DOI：

  10.1081/sim-120015084