| 1401283-50-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• CAS: 1401283-50-8
• 化学式: C₂₈H₂₂CoN₁₂S₂*NO₃
• 分子量: 711.693
• InChiKey: DGQLQOUGFCHQNL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 cobalt(II) nitrate hexahydrate 、 1-甲基-5-巯基-1H-四氮唑 在 sodium hydroxide 作用下， 以 水 为溶剂， 反应 3.0h， 以60%的产率得到
  参考文献：
  名称：

  Three Co^II/Co^III complexes with a 1-substituted tetrazole-5-thiol ligand

  摘要：

  1-Methyl-5-mercapto-tetrazole (mmtz) reacts with Co(II) salts in the presence of N-containing ligands and three Co-II/Co-III complexes, [Co-II(mmtz)(2)(4,4'-bipy)(H2O)(2)](n) (1), [Co-III(mmtz)(2) (1,10-phen)(2)]NO3 (2), and [Co-2(III)(mmtz)(2)(2,2'-bipy)(2)(mu-OH)(2)]Cl-2 (3), have been characterized using single-crystal X-ray diffraction structure determination, IR, and elemental analysis. Complex 1 has a 1-D polymeric structure with neutral [Co(mmtz)(2)(4,4'-bipy)(H2O)(2)] as repeating unit. These 1-D infinite chains are further connected into a 3-D supramolecular framework through intermolecular hydrogen bonds. In 2, mmtz is an S-bonding ligand to form a mononuclear structure. In 3, mmtz as a mu(2) bridging ligand links Co(III) ions to form a dimeric structure. Thermostability of 2 and 3 and electrochemical properties of 1-3 are discussed.

  DOI：

  10.1080/00958972.2012.723205