[Ag4(9-anthracenecarboxylate)4(NH3)2 | 1093124-95-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: [Ag4(9-anthracenecarboxylate)4(NH3)2
• 英文别名: [Ag4(9-aca)4(NH3)2]
• CAS: 1093124-95-8
• 化学式: C₆₀H₄₂Ag₄N₂O₈
• 分子量: 1350.47
• InChiKey: BCMSLKQIOBQIMU-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  9-蒽甲酸 、 氨 、 silver nitrate 以 乙醇 、 水 为溶剂， 以45%的产率得到[Ag4(9-anthracenecarboxylate)4(NH3)2
  参考文献：
  名称：

  [Ag2(aca)2]n and [Ag4(aca)4(NH3)2] (acaH=9-anthracenecarboxylic acid): Synthesis, X-ray crystal structures, antimicrobial and anti-cancer activities

  摘要：

  [Ag-2(9-aca)(2)](n) and [Ag-4(9-aca)(4)(NH3)(2)] (9-acaH = 9-anthracenecarboxylic acid) have been prepared and structurally characterized. [Ag-2(9-aca)(2)](n), consists of polymeric ribbons of linked disilver(I) syn-syn bridged dicarboxylate units. [Ag-4(9-aca)(4)(NH3)(2)] is tetrameric and centrosymmetric, with two syn-syn bridging carboxylates linked to the bimetallic Ag-Ag core and a further two syn-anti bridged carboxylate ligands in the equatorial plane, being coordinated to one Ag in the bimetallic core and to a second Ag, with the latter also bonded to an NH3 ligand. In vitro studies show that both complexes are extremely cytotoxic against selected human fungal and bacterial pathogens, and each complex also greatly inhibits the growth of two mammalian cancer cell lines. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.06.021