η6-phenylacetone-η5-cyclopentadienyliron hexafluorophosphate | 107407-23-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: η6-phenylacetone-η5-cyclopentadienyliron hexafluorophosphate
• 英文别名: (η5-cyclopentadienyl)(η6-1-phenyl-2-propanone)iron(II) hexafluorophosphate(V)；cyclopenta-1,3-diene;iron(2+);1-phenylpropan-2-one;hexafluorophosphate
• CAS: 107407-23-8
• 化学式: C₁₄H₁₅FeO*F₆P
• 分子量: 400.084
• InChiKey: QBMRGDUTBRWLDN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  在 盐酸 作用下， 以 甲醇 为溶剂， 以89%的产率得到η6-phenylacetone-η5-cyclopentadienyliron hexafluorophosphate
  参考文献：
  名称：

  Gill, U. S.; Moriarty, R. M., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1986, vol. 16, p. 485 - 490

  摘要：

  DOI：

文献信息

• Reaction of Mercury(II) Trifluoroacetate with Deprotonated ( ⁶-Toluene)-, ( ⁶-Diphenylmethane)-, and ( ⁶-Triphenylmethane)( ⁵-cyclopentadienyl)iron(II) Complexes. Mercuration of Some Cationic (Arene)(cyclopentadienyl)iron(II) Complexes
  作者：A. M. Boev、A. I. Moskalenko、V. I. Boev

  DOI：10.1023/b:rugc.0000016024.46430.89

  日期：2003.10

  Treatment with mercury(II) trifluoroacetate of deprotonated (eta(6)-toluene)- and (eta(6)-diphenylmethane)(eta(5)-cyclopentadienyl)iron(II) complexes gave mono-, di-, and trisubstituted [from (eta(6)-toluene)(eta(5)-cyclopentadienyl)iron(II) cation] mercury-containing salts. The reaction of mercury(II) trifluoroacetate with deprotonated (eta(6)-triphenylmethane)(eta(5)-cyclopentadienyl)iron(II) afforded only the corresponding symmetric mercury derivative. The same product was obtained by direct mercuration with mercury(II) trifluoroacetate of (eta(6)-triphenylmethane)(eta(5)-cyclopentadienyl)iron(II) on heating the reactants in boiling unhydrous ethanol. Reactions of the resulting mercury-containing compounds with acids, symmetrizing bases, and acylating agents were studied.
• Lee, C. C.; Abd-El-Aziz, A. S.; Chowdhury, R. L., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1986, vol. 16, p. 541 - 552
  作者：Lee, C. C.、Abd-El-Aziz, A. S.、Chowdhury, R. L.、Piorko, A.、Sutherland, R. G.

  DOI：——

  日期：——