4-Pyridyl-Radikal | 29761-82-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-Pyridyl-Radikal
• CAS: 29761-82-8
• 化学式: C₅H₄N
• 分子量: 78.0935
• InChiKey: XKLOYCALBFDZLY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  以 氨 为溶剂， 生成 4-Pyridyl-Radikal 、 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Theory and experimental illustration of preparative electrochemistry using redox catalysis of electron transfer initiated radical chain reactions. Application to the cross-coupling between aryl halides and phenoxide ions

  摘要：

  A general equation predicting the yield of electron transfer initiated radical chain reaction (S(RN)1 and related mechanisms) under preparative electrochemical conditions is given for situations where the electron-transfer activation of the chain is performed by means of a redox mediator. Simple tests, allowing for the choice of proper redox mediator, are given, and their origins established and discussed. The validity and application of this simple model is shown and discussed for the case of the S(RN)1-like reaction involving di-tert-butylphenoxide as a nucleophile, to afford biaryls of interest for their properties in nonlinear optics.

  DOI：

  10.1021/jo00313a022

文献信息

• Cathodic cleavage of heteroarylalkylsulfones : A facile route to long chain aliphatic sulfinates and relevant sulfones.
  作者：Jacques Delaunay、Gilles Mabon、Mohamed Chaquiq El Badre、Armelle Orliac、Jacques Simonet

  DOI：10.1016/0040-4039(92)88163-y

  日期：1992.4

  Heteroarylalkylsulfones -mainly pyridylalkylsulfones- exhibit a cathodic cleavage reaction producing alkanesulfinate anion in high yield. This reaction is tested with long chain alkyl groups and allows an easy synthesis of aliphatic sulfinic acids.