cobalt(II) phenylphosphonate monohydrate | 45986-29-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cobalt(II) phenylphosphonate monohydrate
• 英文别名: cobalt phenylphosphonate monohydrate；cobalt phenylphosphonate hydrate
• CAS: 45986-29-6
• 化学式: C₆H₅O₃P*Co*H₂O
• 分子量: 233.086
• InChiKey: YGSMTPUPCNNETG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.6
• 重原子数：
  12.0
• 可旋转键数：
  1.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  94.69
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  cobalt(II) phenylphosphonate monohydrate 在 air 作用下， 以 neat (no solvent) 为溶剂， 生成 cobalt(II) pyrophosphate
  参考文献：
  名称：

  Selected-Control Synthesis of Metal Phosphonate Nanoparticles and Nanorods

  摘要：

  By surfactant-assisted methods, nanoscale Co(O3PC6H5)center dot H2O species of different morphologies, namely, nanoparticles and nanorods, have been successfully synthesized and characterized. Upon removal of the organic part of the compound, peculiar Co2P2O7 porous nanorods formed.

  DOI：

  10.1021/ic048436t
• 作为产物：
  描述：

  CoPPA 在 H₂O 作用下， 以 neat (no solvent) 为溶剂， 生成 cobalt(II) phenylphosphonate monohydrate
  参考文献：
  名称：

  Frink, Karen J.; Wang, Ren-Chain; Colón, Jorge L., Inorganic Chemistry, 1991, vol. 30, # 7, p. 1438 - 1441

  摘要：

  DOI：

文献信息

• Direct In Situ Investigation of Milling Reactions Using Combined X-ray Diffraction and Raman Spectroscopy
  作者：Lisa Batzdorf、Franziska Fischer、Manuel Wilke、Klaus-Jürgen Wenzel、Franziska Emmerling

  DOI：10.1002/anie.201409834

  日期：2015.2.2

  time‐resolved in situ X‐ray diffraction (XRD) and Raman spectroscopy provides a new opportunity for a detailed analysis of the key mechanisms of milling reactions. To prove the general applicability of our setup, we investigated the mechanochemical synthesis of four archetypical model compounds, ranging from 3D frameworks through layered structures to organic molecular compounds. The reaction mechanism for

  两种分析方法的结合，包括时间分辨原位X射线衍射（XRD）和拉曼光谱，为研磨反应关键机理的详细分析提供了新的机会。为了证明我们装置的一般适用性，我们研究了4种原型模型化合物的机械化学合成，其范围从3D框架到分层结构再到有机分子化合物。可以阐明每种模型化合物的反应机理。结果清楚地表明，由于两种方法的信息含量和动态范围不同，因此XRD和拉曼光谱法相结合的独特优势。
• Hydrothermal synthesis and characterization of a layered cobalt phenylphosphonate, Co(PhPO₃)(H₂O)
  作者：T. O. Salami、X. Fan、P. Y. Zavalij、S. R. J. Oliver

  DOI：10.1039/b510942f

  日期：——

  We report the hydrothermal synthesis and characterization of a layered cobalt phenylphosphonate. Unlike most metal phosphonates reported to date, the structure was solved by single crystal X-ray diffraction (SC-XRD). Co(II) centres are hexa-coordinated by oxygen and the octahedra corner-share into a layer. The layers are capped by phenylphosphonate groups, where the phenyl groups define a hydrophobic bilayer region. The material was also characterized by powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) and SQUID (superconducting quantum interference device) magnetometry. The material undergoes an antiferromagnetic transition at a relatively low Néel temperature of 4.0 K, while the Curie–Weiss temperature of −76.5 K reflects the low-dimensionality of the magnetic structure. The effective magnetic moment of 5.01 µB per Co2+ verifies a high-spin configuration and an octahedral coordination of the metal centres. This layered material was correctly predicted in the literature from powder data, adds to the structural diversity of the cobalt phosphonates, and may be useful as an intercalation or exfoliation compound.

  我们报告了一种层状苯基膦酸钴的水热合成和表征。与迄今报道的大多数金属膦酸盐不同，该化合物的结构是通过单晶 X 射线衍射 (SC-XRD) 解决的。钴（II）中心是由氧配位的六面体，八面体角共享成一层。这些层由苯基膦酸盐基团封盖，其中苯基基团定义了一个疏水双层区域。该材料还通过粉末 X 射线衍射 (PXRD)、热重分析 (TGA) 和 SQUID（超导量子干涉装置）磁力测定法进行了表征。该材料在相对较低的奈尔温度（4.0 K）下发生反铁磁转变，而居里-韦斯温度（-76.5 K）则反映了磁性结构的低维性。每 Co2+ 5.01 µB 的有效磁矩验证了高自旋构型和金属中心的八面体配位。这种层状材料是根据文献中的粉末数据正确预测出来的，增加了膦酸钴结构的多样性，可用作插层或剥离化合物。
• Layered Mixed-Metal Phenylphosphonates, MnxCo1−x(O3PC6H5)·H2O: Structure and Magnetic Properties
  作者：Jeffrey T. Culp、Gail E. Fanucci、Brian C. Watson、A. Nicole Morgan、Rénal Backov、Hitoshi Ohnuki、Mark W. Meisel、Daniel R. Talham

  DOI：10.1006/jssc.2001.9166

  日期：2001.7

  of the magnetic data for the pure Mn2+ (x=1) and pure Co2+ (x=0) samples was fitted by standard 2D Heisenberg and 2D Ising models, respectively, yielding nearest-neighbor exchange interaction energies of J=−2.27±0.02 K for Mn(O3PC6H5)·H2O and J=−2.43±0.05 K for Co(O3PC6H5)·H2O. The magnetic phase diagram, down to 2 K, was constructed over the entire composition range. Both dc and ac magnetic susceptibilities

  组合物的Mn混合金属phenylphosphonates X钴1- X（O 3 PC 6 ħ 5）·H 2用0≤制备ö X ≤1。原子吸收，X射线粉末衍射和电子顺磁共振测量表明，混合金属固体溶液是均匀的并且同构，在整个浓度范围内的单金属母体化合物，与所述的一个小的，系统进化一个和ç面内的晶胞参数。磁数据的对于纯的Mn的温度依赖性2+（X = 1）和纯钴2+（X = 0）的样本进行拟合通过标准的2D海森堡和2D伊辛模型，分别得到的最近邻居交换相互作用能量Ĵ = -2.27±0.02 K中的Mn（O 3 PC 6 ħ 5）·H 2 O和Ĵ = -2.43±0.05 K中钴（O 3 PC 6 ħ 5）·H 2 O的磁性相图，下降到2 K，构建在整个组合物范围内。直流和交流磁化率均用于识别向低温，长距离有序反铁磁态的跃迁。在锰2+ -和Co 2+富集的地区，有序化温度，Ť Ñ，如预期的磁离子杂质掺
• <i>In situ</i> fabrication of a rose-shaped Co₂P₂O₇/C nanohybrid <i>via</i> a coordination polymer template for supercapacitor application
  作者：Jiaxin Zhang、Peng Liu、Ranran Bu、Hao Zhang、Qi Zhang、Kang Liu、Yanru Liu、Zhenyu Xiao、Lei Wang

  DOI：10.1039/d0nj02414g

  日期：——

  Using a coordination polymer as the template, the porous rose-shaped Co₂P₂O₇/C-X were fabricated by in situ hybrid Co₂P₂O₇ nanoparticles and nanocarbon for supercapacitor applications.

  使用配位聚合物作为模板，通过原位杂化Co2P2O7纳米颗粒和纳米碳制备了多孔玫瑰形Co2P2O7/C-X材料，用于超级电容器应用。
• Divalent metal phenylphosphonates and phenylarsonates
  作者：Desmond Cunningham、Patrick J.D. Hennelly、Tony Deeney

  DOI：10.1016/s0020-1693(00)95524-5

  日期：1979.1