N,N-dimethylselenocarbamoyl chloride | 307000-91-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-dimethylselenocarbamoyl chloride
• 英文别名: N,N-dimethylcarbamoselenoyl chloride
• CAS: 307000-91-5
• 化学式: C₃H₆ClNSe
• 分子量: 170.5
• InChiKey: GDZARGVNSMJUOO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.04
• 重原子数：
  6
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  lithium phenylmethanethiolate 、 N,N-dimethylselenocarbamoyl chloride 以 四氢呋喃 为溶剂， 反应 2.0h， 以0.17 g的产率得到S-benzyl N,N-dimethylselenothiocarbamate
  参考文献：
  名称：

  Reaction of N,N-Dimethylselenocarbamoyl Chloride with Nucleophiles. Preparation of Diselenocarbamates, Selenothiocarbamates, and Selenoureas

  摘要：

  Reactions of N,N-dimethylselenocarbamoyl chloride prepared by using LiAlHSeH with nucleophiles such as lithium alkylselenolate, lithium alkylthiolate, and amines afford the corresponding diselenocarbamates, selenothiocarbamates, and selenoureas. The crystal structure of the Se-phenyl N,N-dimethyldiselenocarbamate was also determined by X-ray diffraction.

  DOI：

  10.1021/jo015872d
• 作为产物：
  描述：

  二氯亚甲基二甲基氯化铵 在 LiAlHSeH 作用下， 以 四氢呋喃 为溶剂， 反应 1.5h， 生成 N,N-dimethylselenocarbamoyl chloride
  参考文献：
  名称：

  Reaction of N,N-Dimethylselenocarbamoyl Chloride with Nucleophiles. Preparation of Diselenocarbamates, Selenothiocarbamates, and Selenoureas

  摘要：

  Reactions of N,N-dimethylselenocarbamoyl chloride prepared by using LiAlHSeH with nucleophiles such as lithium alkylselenolate, lithium alkylthiolate, and amines afford the corresponding diselenocarbamates, selenothiocarbamates, and selenoureas. The crystal structure of the Se-phenyl N,N-dimethyldiselenocarbamate was also determined by X-ray diffraction.

  DOI：

  10.1021/jo015872d

文献信息

• Synthesis, crystal structure and electrochemical properties of bis(ethylenedioxy)tetraselenafulvalene (BEDO-TSeF)
  作者：Tatsuro Imakubo、Takashi Shirahata、Megumi Kibune

  DOI：10.1039/b403559c

  日期：——

  Bis(ethylenedioxy)tetraselenafulvalene (BEDO-TSeF) has been synthesized using elemental selenium as the only source of the selenium atoms, and its crystal structure and electrochemical properties are examined and compared with its sulfur analogues.

  使用元素硒作为硒原子的唯一来源合成了双（乙二氧基）四硒富勒烯（BEDO-TSeF），并对其晶体结构和电化学性质进行了比较，并与它的硫类似物进行了比较。
• Reaction of <i>N</i>,<i>N</i>-Dimethylselenocarbamoyl Chloride with Nucleophiles. Preparation of Diselenocarbamates, Selenothiocarbamates, and Selenoureas
  作者：Mamoru Koketsu、Yoshihisa Fukuta、Hideharu Ishihara

  DOI：10.1021/jo015872d

  日期：2002.2.1

  Reactions of N,N-dimethylselenocarbamoyl chloride prepared by using LiAlHSeH with nucleophiles such as lithium alkylselenolate, lithium alkylthiolate, and amines afford the corresponding diselenocarbamates, selenothiocarbamates, and selenoureas. The crystal structure of the Se-phenyl N,N-dimethyldiselenocarbamate was also determined by X-ray diffraction.