tris(2-tert-butyl-4-phenylphenyl)phosphite | 31502-44-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tris(2-tert-butyl-4-phenylphenyl)phosphite
• 英文别名: Tris(2-tert-butyl-4-phenylphenyl) phosphite
• CAS: 31502-44-0
• 化学式: C₄₈H₅₁O₃P
• 分子量: 706.905
• InChiKey: JIKOHGNZNKFYHF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.4
• 重原子数：
  52
• 可旋转键数：
  12
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• Process for the preparation of acid esters
  申请人：General Electric Company

  公开号：US20040059151A1

  公开（公告）日：2004-03-25

  The present invention is directed to a process for the preparation of sterically hindered acid esters, e.g., organic phosphites, comprising contacting a sterically hindered hydroxyl-containing compound with an acid halide in the presence of an acid acceptor selected from the group consisting of: 1,5-diazabicyclo[4.3.0]non-5-ene (DBN), 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), 4-(dimethylamino)pyridine (DMAP), 1,4-diazabicyclo[2.2.2]octane (DABCO), or mixtures thereof, wherein said an acid acceptor is present in an amount sufficient to drive the reaction to completion.

  本发明涉及一种制备立体位阻酸酯的方法，例如有机磷酸酯，包括将立体位阻羟基化合物与酸卤在酸受体的存在下接触，所述酸受体选自以下组中的一种：1,5-二氮杂双环[4.3.0]壬-5-烯（DBN）、1,8-二氮杂双环[5.4.0]十一烷-7-烯（DBU）、4-（二甲氨基）吡啶（DMAP）、1,4-二氮杂双环[2.2.2]辛烷（DABCO）或其混合物，其中所述酸受体的存在量足以将反应推向完成。
• POLYACETAL RESIN COMPOSITION AND MOLDINGS
  申请人：——

  公开号：US20030158301A1

  公开（公告）日：2003-08-21

  The polyacetal resin composition contains about 0.01-10 parts by weight of a glyoxyldiureide compound per 100 parts by weight of polyacetal resin. The glyoxyldiureide compound includes glyoxyldiureide and its derivatives (metal salts etc.). Optionally, about 0.01-10 parts by weight of a basic nitrogen-containing compound is further added. The basic nitrogen-containing compound includes melamine, melamine resin, and polyamide resin. Further, an antioxidant may be further added. The above composition contributes to stability, particularly heat stability, of polyacetal resin and suppression of emission of formaldehyde.

  聚乙二醇树脂组成物含有每100份聚乙二醇树脂约0.01-10份重量的甘氧基二脲化合物。该甘氧基二脲化合物包括甘氧基二脲及其衍生物（金属盐等）。可选择地，还可进一步添加约0.01-10份重量的碱性含氮化合物。碱性含氮化合物包括三聚氰胺、三聚氰胺树脂和聚酰胺树脂等。此外，还可以进一步添加抗氧化剂。以上组成物有助于提高聚乙二醇树脂的稳定性，特别是热稳定性，并抑制甲醛的排放。
• Polyacetal resin composition and moldings
  申请人：Harashina Hatsuhiko

  公开号：US20050075429A1

  公开（公告）日：2005-04-07

  The polyacetal resin composition contains about 0.01-10 parts by weight of a glyoxyldiureide compound per 100 parts by weight of polyacetal resin. The glyoxyldiureide compound includes glyoxyldiureide and its derivatives (metal salts etc.). Optionally, about 0.01-10 parts by weight of a basic nitrogen-containing compound is further added. The basic nitrogen-containing compound includes melamine, melamine resin, and polyamide resin. Further, an antioxidant may be further added. The above composition contributes to stability, particularly heat stability, of polyacetal resin and suppression of emission of formaldehyde.

  聚乙二醇树脂组合物含有每100份聚乙二醇树脂约0.01-10份重量的乙酰基尿素化合物。乙酰基尿素化合物包括乙酰基尿素及其衍生物（金属盐等）。可选地，还可以进一步添加约0.01-10份重量的含有碱性氮化合物。碱性氮化合物包括三聚氰胺，三聚氰胺树脂和聚酰胺树脂。此外，还可以进一步添加抗氧化剂。上述组合物有利于聚乙二醇树脂的稳定性，特别是热稳定性，并抑制甲醛的排放。
• Resin Composition and Composite Using the Composition and Production Process Thereof
  申请人：Ikuta Toru

  公开号：US20070292703A1

  公开（公告）日：2007-12-20

  A resin composition comprises a resin, a vulcanization-activating agent, and a stabilizer. The vulcanization-activating agent may be a compound having a plurality of polymerizable unsaturated bonds (e.g., a compound having a plurality of (meth)acryloyl groups). The stabilizer may be an antioxidant, or a light stabilizer (particularly, a stabilizer is capable of capturing a radical). Use of the resin composition as a resin material ensures to directly join between a resin and a rubber certainly and firmly. The proportion of the vulcanization-activating agent may be about 0.1 to 10 parts by weight relative to 100 parts by weight of the resin. The proportion of the stabilizer may be about 0.01 to 5 parts by weight relative to 100 parts by weight of the resin. The present invention provides a resin composition excellent in adhesiveness to a rubber.

  一种树脂组合物包括树脂、一种硫化活化剂和一种稳定剂。硫化活化剂可以是一种具有多个可聚合不饱和键的化合物（例如，具有多个（甲基）丙烯酰基基团的化合物）。稳定剂可以是一种抗氧化剂或光稳定剂（特别是能够捕获自由基的稳定剂）。使用该树脂组合物作为树脂材料确保树脂和橡胶之间直接连接牢固。硫化活化剂的比例可以是相对于100份树脂重量约0.1至10份重量。稳定剂的比例可以是相对于100份树脂重量约0.01至5份重量。本发明提供了一种对橡胶具有优异粘附性的树脂组合物。
• RESIN COMPOSITION AND COMPOSITE USING THE COMPOSITION AND PRODUCTION PROCESS THEREOF
  申请人：IKUTA Toru

  公开号：US20100215964A1

  公开（公告）日：2010-08-26

  A resin composition comprises a resin, a vulcanization-activating agent, and a stabilizer. The vulcanization-activating agent may be a compound having a plurality of polymerizable unsaturated bonds (e.g., a compound having a plurality of (meth)acryloyl groups). The stabilizer may be an antioxidant, or a light stabilizer (particularly, a stabilizer is capable of capturing a radical). Use of the resin composition as a resin material ensures to directly join between a resin and a rubber certainly and firmly. The proportion of the vulcanization-activating agent may be about 0.1 to 10 parts by weight relative to 100 parts by weight of the resin. The proportion of the stabilizer may be about 0.01 to 5 parts by weight relative to 100 parts by weight of the resin. The present invention provides a resin composition excellent in adhesiveness to a rubber.

  一种树脂组合物包括树脂、硫化活性剂和稳定剂。硫化活性剂可以是具有多个可聚合不饱和键的化合物（例如，具有多个（甲基）丙烯酰基基团的化合物）。稳定剂可以是抗氧化剂或光稳定剂（特别是具有捕获自由基能力的稳定剂）。使用该树脂组合物作为树脂材料可确保树脂与橡胶之间的直接连接牢固可靠。硫化活性剂的比例可以是相对于100份树脂的0.1至10份重量。稳定剂的比例可以是相对于100份树脂的0.01至5份重量。本发明提供了一种在与橡胶粘附性方面表现出色的树脂组合物。