(chlorophenothiazine)2PdCl2 | 81447-17-8

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: (chlorophenothiazine)2PdCl2
• 英文别名: bis(4-chloro-10H-phenothiazin-10-yl)palladium(IV) chloride
• CAS: 81447-17-8；75248-66-7
• 化学式: C₂₄H₁₆Cl₄N₂PdS₂
• 分子量: 644.768
• InChiKey: PEIUAVAJAYZTFQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-chlorophenothiazine 、 palladium dichloride 以 乙醇 为溶剂， 生成 (chlorophenothiazine)2PdCl2
  参考文献：
  名称：

  Gowda, H. Sanke; Jayarama, Journal of the Less-Common Metals, 1980, vol. 72, p. P37 - P42

  摘要：

  DOI：

文献信息

• Palladium(II)-phenothiazine complexes: synthesis and characterization
  作者：Netkal M.Made Gowda、Ravindra K. Vallabhaneni、Indira Gajula、S. Ananda

  DOI：10.1016/s0022-2860(96)09750-5

  日期：1997.5

  Palladium(II) chloride or nitrate complexes of phenothiazine and its derivatives have been prepared. The new complexes were characterized by their elemental analyses, molar conductivity, magnetic susceptibility and spectroscopic data. The molecular formulae of the complexes were found to be: [C12H9NS)(2)PdCl2].H2O where C12H9NS = phenothiazine (PTZ); [C12H8CINS)(2)PdCl2] where C12H8CINS = 2-chlorophenothiazine (CPTZ); [(C21H27N2S2)Pd2Cl5].2H(2)O where (C21H27N2S2)(+) = protonated thioridazine (TRH+); and [(C17H21N2S2)(2)Pd2Cl5]NO3 where (C17H21N2S)(+) = protonated promethazine (PMH+). The PM complex behaves as an electrolyte whereas the other complexes act as nonelectrolytes in solution. All the complexes an diamagnetic species. Tentative structures have been proposed. (C) 1997 Elsevier Science B.V.