3-O-benzyl-1,2-O-isopropylidene-5,6-deoxy-5,6-(N-tert-butylsulfonyl)imino-α-D-glucofuranose | 1426445-16-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-O-benzyl-1,2-O-isopropylidene-5,6-deoxy-5,6-(N-tert-butylsulfonyl)imino-α-D-glucofuranose
• CAS: 1426445-16-0
• 化学式: C₂₀H₂₉NO₆S
• 分子量: 411.519
• InChiKey: MIRUBHBYZZZARP-MFLXRBJJSA-N

反应信息

• 作为产物：
  描述：

  在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 0.02h， 以133.7 mg的产率得到3-O-benzyl-1,2-O-isopropylidene-5,6-deoxy-5,6-(N-tert-butylsulfonyl)imino-α-D-glucofuranose
  参考文献：
  名称：

  Stereoselective Synthesis of Carbohydrate-Derived N-Sulfonyl Aziridines

  摘要：

  A novel reaction of iodomethyllithium with a variety of sugar-derived N-sulfinyl imines, under very mild conditions, is described. N-Sulfonyl aziridines were easily obtained in high yields and in moderate to good stereoselectivities through an addition/oxidation protocol. A mechanism is proposed that is supported by the results of X-ray diffraction studies.

  DOI：

  10.1055/s-0032-1317954