chloro-5-aminouracilmethioninepalladium(II)chloride | 145116-09-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 咪唑并嘧啶类
• 英文名称: chloro-5-aminouracilmethioninepalladium(II)chloride
• CAS: 145116-09-2
• 化学式: C₉H₁₆ClN₄O₄PdS*Cl
• 分子量: 453.642
• InChiKey: XBGLOBJUXFSNLL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  5-氨基尿嘧啶 、 (R-methionine)palladium(II) dichloride 以 水 为溶剂， 生成 chloro-5-aminouracilmethioninepalladium(II)chloride
  参考文献：
  名称：

  Mixed ligand complexes of cis-dichloromethionineplatinum(II) and cis-dichloromethioninepalladium(II) with substituted pyrimidines

  摘要：

  Mixed ligand complexes of cis-dichloromethionineplatinum(II), [Pt(meth)Cl2], with pyrimidines, 2-hydroxypyrimidinehydrochloride, 5-aminouracil, 2-thiocytosine, isocytosine and mixed ligand complexes of cis-dichloromethioninepalladium(II), [Pd(meth)Cl2], with pyrimidines, 2-hydroxypyrimidinchydrochloride, 5-aminouracil and 4,6-diamino-2-thiopyrimidine were synthesized and characterized by elemental analysis, IR, UV, H-1 NMR and C-13 NMR spectra. In these mixed ligand complexes methionine coordinates to the metal ion through sulphur and the amino nitrogen, thus leaving a free carboxylic acid group. The pyrimidines, 2-hydroxypyrimidinehydrochloride, 4,6-diamino-2-thiopyrimidine, isocytosine and 2-thiocytosine act as monodentate ligands and bind to the metal ion through N3, while 5-aminouracil coordinates to the metal ion through the amino (NH2) group.

  DOI：

  10.1016/s0277-5387(00)83168-x