(2'R)-[2'-(N-benzylideneamino)butyl]tetraethyldiamidophosphite | 418779-53-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2'R)-[2'-(N-benzylideneamino)butyl]tetraethyldiamidophosphite
• CAS: 418779-53-0
• 化学式: C₁₉H₃₄N₃OP
• 分子量: 351.472
• InChiKey: IEISKRBPDQUSHO-IBGZPJMESA-N

反应信息

• 作为反应物：
  描述：

  di(rhodium)tetracarbonyl dichloride 、 (2'R)-[2'-(N-benzylideneamino)butyl]tetraethyldiamidophosphite 以 二氯甲烷 为溶剂， 以87%的产率得到chlorocarbonyl[(2'R)-[2'-(N-benzylideneamino)butyl]tetraethyldiamidophosphite]rhodium
  参考文献：
  名称：

  摘要：

  Optically active amidophosphite with the peripheral imino group (R)(Et2N)2POCH(2)CH(Et)N=CHPh is synthesized through one-stage phosphorylation of the corresponding imino alcohol. Its reaction with [Rh(CO)(2)Cl](2) (at P: Rh = 1) yields the mononuclear chelate [Rh(CO)(P<^>N)Cl]. Structures of the compounds are determined by IR, P-31, and C-13 NMR spectroscopy, mass spectrometry, and polarimetry.

  DOI：

  10.1023/a:1014244404085